Beryllium oxide (BeO) belongs to
a very unique material family
that exhibits the divergent properties of high thermal conductivity
and high electrical resistivity. BeO has the same crystal structure
as GaN, and the absolute difference in the lattice constants is less
than 17%. Here, the growth of GaN nanowires (NWs) on the polycrystalline
BeO substrate is reported for the first time. The NWs are grown by
a vapor–liquid–solid approach using a showerhead-based
metal–organic chemical vapor deposition. The growth direction
of NWs is along the
m
-axis on all planes of the substrate,
and it is confirmed by transmission electron microscopy (TEM) and
selected area electron diffraction (SAED) patterns. The vertical and
tilted growth of NWs is due to the different planes of the substrate
such as the
m
-plane,
a
-plane, and
semipolar planes and is confirmed by X-ray diffraction. Subsequently,
the GaN shell and InGaN/GaN multiple quantum wells (MQWs) are coaxially
grown using a vapor–solid approach in the same reactor. A very
high crystal quality is verified by TEM and SAED and is also confirmed
by measuring the photoluminescence. The optical emission is tuned
for the entire visible spectrum by increasing the indium incorporation
in InGaN quantum wells. The conformal growth of InGaN/GaN MQW shells
and the defect-free nature of the structure are confirmed from spatially
resolved cathodoluminescence. This study will provide a platform for
researchers to grow GaN NWs on the BeO substrate for a range of optical
and electrical applications.