Ultrafast laser plasma assisted rare-earth doping for silicon photonics

Jose, Gin; Chandrappan, Jayakrishnan; Kamil, Suraya Ahmad; Murray, M.; Zolnai, Zsolt; Agócs, Emil; Petrik, P.; Steenson, Paul; Krauss, Thomas F.

doi:10.1364/cleo_at.2016.atu3k.5

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“…The surface implantation and dissolution of ions and nanoparticles produced by the femtosecond laser-induced plasma into the substrate surface network results in the structural modification of the substrate surface [ 17 ]. Previous studies have proven Er-TZN to be successfully doped into silica [ 13 , 15 , 16 , 18 , 19 , 20 ]. Since this process is also assisted by substrate heating during the doping process, selecting the appropriate temperature is very critical.…”

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confidence: 99%

Effect of Substrate Temperature on Morphological, Structural, and Optical Properties of Doped Layer on SiO2-on-Silicon and Si3N4-on-Silicon Substrate

Kamil

Jose

2022

Nanomaterials

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A high concentration of Er3+ without clustering issues is essential in an Er-doped waveguide amplifier as it is needed to produce a high gain and low noise signal. Ultrafast laser plasma doping is a technique that facilitates the blending of femtosecond laser-produced plasma from an Er-doped TeO2 glass with a substrate to form a high Er3+ concentration layer. The influence of substrate temperature on the morphological, structural, and optical properties was studied and reported in this paper. Analysis of the doped substrates using scanning electron microscopy (SEM) confirmed that temperatures up to approximately 400 °C are insufficient for the incoming plasma plume to modify the strong covalent bonds of silica (SiO2), and the doping process could not take place. The higher temperature used caused the materials from Er-doped tellurite glass to diffuse deeper (except Te with smaller concentration) into silica, which created a thicker film. SEM images showed that Er-doped tellurite glass was successfully diffused in the Si3N4. However, the doping was not as homogeneous as in silica.

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