Ultrafast X-Ray Scattering Measurements of Coherent Structural Dynamics on the Ground-State Potential Energy Surface of a Diplatinum Molecule

Haldrup, Kristoffer; Levi, Gianluca; Biasin, Elisa; Vester, Peter; Laursen, Mads G.; Beyer, Frederik; Kjær, Kasper Skov; Driel, Tim Brandt van; Harlang, Tobias; Dohn, Asmus Ougaard; Hartsock, Robert J.; Nelson, S.; Glownia, James M.; Lemke, Henrik T.; Christensen, Morten; Gaffney, Kelly J.; Henriksen, Niels Engholm; Møller, Klaus Braagaard; Nielsen, Martin Meedom

doi:10.1103/physrevlett.122.063001

Cited by 80 publications

(89 citation statements)

References 73 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…We close our discussion by noting that vibrational dynamics of other photoactivated transition metal complexes have also been observed experimentally by elastic TR-XDS. 65,68,69…”

Section: B Elastic X-ray Scatteringmentioning

confidence: 99%

Simulation of ultrafast excited-state dynamics and elastic x-ray scattering by quantum wavepacket dynamics

Pápai

Rozgonyi

Penfold

et al. 2019

The Journal of Chemical Physics

Self Cite

View full text Add to dashboard Cite

 Users may download and print one copy of any publication from the public portal for the purpose of private study or research.  You may not further distribute the material or use it for any profit-making activity or commercial gain  You may freely distribute the URL identifying the publication in the public portal If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim.

show abstract

“…We close our discussion by noting that vibrational dynamics of other photoactivated transition metal complexes have also been observed experimentally by elastic TR-XDS. 65,68,69…”

Section: B Elastic X-ray Scatteringmentioning

confidence: 99%

Simulation of ultrafast excited-state dynamics and elastic x-ray scattering by quantum wavepacket dynamics

Pápai

Rozgonyi

Penfold

et al. 2019

The Journal of Chemical Physics

Self Cite

View full text Add to dashboard Cite

show abstract

“…Coherent nuclear dynamics are ubiquitous in photoexcited systems. Oscillatory wavepacket motions have been clearly measured in time-resolved WAXS [19,27,32], however the effects of purely nuclear dynamics in ultrafast Kα/Kβ XES has not been observed [10][11][12][13][14]. This contrasts with other X-ray spectroscopic methods that directly involve valence orbitals, such as X-ray absorption [33][34][35][36][37][38] and resonant inelastic X-ray scattering [39][40][41], which are sensitive to both electronic and nuclear structure.…”

Section: Introductionmentioning

confidence: 99%

Vibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering

et al. 2020

Self Cite

View full text Add to dashboard Cite

The non-equilibrium dynamics of electrons and nuclei govern the function of photoactive materials. Disentangling these dynamics remains a critical goal for understanding photoactive materials. Here we investigate the photoinduced dynamics of the [Fe(bmip)2]2+ photosensitizer, where bmip = 2,6-bis(3-methyl-imidazole-1-ylidine)-pyridine, with simultaneous femtosecond-resolution Fe Kα and Kβ X-ray emission spectroscopy (XES) and X-ray solution scattering (XSS). This measurement shows temporal oscillations in the XES and XSS difference signals with the same 278 fs period oscillation. These oscillations originate from an Fe-ligand stretching vibrational wavepacket on a triplet metal-centered (3MC) excited state surface. This 3MC state is populated with a 110 fs time constant by 40% of the excited molecules while the rest relax to a 3MLCT excited state. The sensitivity of the Kα XES to molecular structure results from a 0.7% average Fe-ligand bond length shift between the 1 s and 2p core-ionized states surfaces.

show abstract

“…Some of them are ambitious or even unproven one's in military sector like creation of anti-nuclear neutrino weapon activating as it is expected nuclear warhead remotely or neutrino sources for detection of warheads [20,21]. Projects in biotechnology grasp such knowledge field as application of Vavilov-Cherenkov radiation for the development of biological processes monitoring within living cells in real time [22]. Economically beneficial technology seems to be chemical process study in real time by means of x-ray propagation induced with particle collisions or deceleration [22].…”

Section: Colliders Comparisonmentioning

confidence: 99%

“…Projects in biotechnology grasp such knowledge field as application of Vavilov-Cherenkov radiation for the development of biological processes monitoring within living cells in real time [22]. Economically beneficial technology seems to be chemical process study in real time by means of x-ray propagation induced with particle collisions or deceleration [22]. Beneficial directions can be predictive chemistry, molecules detection and catalytic process tracing in real time with high energy gamma rays, quantum phenomena studying and some other phenomena hardly processed with conventional methods.…”

Section: Colliders Comparisonmentioning

confidence: 99%

Particle colliders market development and evolution models

Заболотский

2020

SN Appl. Sci.

View full text Add to dashboard Cite

Main goal of this article-assessment of scientific projects and their economic impact. This assessment includes economic and technological feasibility on the example of elementary physics collider projects. Methodology includes structural integration in other technological fields by means of self-organizing neural maps and anthological retrospective analysis of radical discoveries with their recent impetus for economic development. Self-organizing neural map helps to expose hidden structural similarities of technology spreading and integration with other technologies. This is a new approach exposing the capacity for technology convergence into other industries. Capacity evaluations for integration and emergence of new technologies on the frontiers of elementary particles physics is provided. Explanation of integration problems in explained. Novelty of the study is based on integration of physical attributes into economics enabling new explanations of technology development models. Risk adjusted net present value evaluation is carried out. Comparison of similar projects around the world created in the article shows common frames and model of collider projects development. Risk adjusted model takes into account integration potential of technology under study. Conclusion combining obtained results in neural maps and historical retrospection is made.

show abstract

Ultrafast X-Ray Scattering Measurements of Coherent Structural Dynamics on the Ground-State Potential Energy Surface of a Diplatinum Molecule

Cited by 80 publications

References 73 publications

Simulation of ultrafast excited-state dynamics and elastic x-ray scattering by quantum wavepacket dynamics

Simulation of ultrafast excited-state dynamics and elastic x-ray scattering by quantum wavepacket dynamics

Vibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering

Particle colliders market development and evolution models

Contact Info

Product

Resources

About