The selective extraction
and recovery of different lignocellulosic
molecules of interest from forestry residues is increasing every day
not only to satisfy the needs of driving a society toward more sustainable
approaches and materials (rethinking waste as a valuable resource)
but also because lignocellulosic molecules have several applications.
For this purpose, the development of new sustainable and ecologically
benign extraction approaches has grown significantly. Deep eutectic
solvents (DESs) appear as a promising alternative for the processing
and manipulation of biomass. In the present study, a DES formed using
choline chloride and levulinic acid (ChCl:LA) was studied to fractionate
lignocellulosic residues of acacia wood (
Acacia dealbata
Link), an invasive species in Portugal. Different parameters, such
as temperature and extraction time, were optimized to enhance the
yield and purity of recovered cellulose and lignin fractions. DESs
containing LA were found to be promising solvent systems, as the hydrogen
bond donor was considered relevant in relation to lignin extraction
and cellulose concentration. On the other hand, the increase in temperature
and extraction time increases the amount of extracted material from
biomass but affects the purity of lignin. The most promising DES system,
ChCl:LA in a ratio of 1:3, was found to not significantly depolymerize
the extracted lignin, which presented a similar molecular weight to
a kraft lignin. Additionally, the
31
P NMR results revealed
that the extracted lignin has a high content of phenolic OH groups,
which favor its reactivity. A mixture of ChCl:LA may be considered
a fully renewable solvent, and the formed DES presents good potential
to fractionate wood residues.