Small firearm shooting emits residues of energetic materials as well as heavy metals of different particle sizes into the air, posing a risk to human health. The current study assessed concentrations of Pb, Cu, Ni and Zn in 14 different size fractions of particulate matter at indoor military shooting ranges. Air samples were collected using ELPI + over two hour period and filters analysed with ICP-MS and ICP-OES.Among the studied metals, Pb concentrations were highest; however, OSHA limit values were only exceeded in one case, when also the highest numbers of gun shots were made. The majority of Pb particles were in fractions > 120 nm. Although concentrations of Cu, Ni, and Zn were significantly lower than Pb, they were more often present as nanoparticles (< 120 nm). This increases their harmfulness, as nanoparticles can easily penetrate the cardiovascular and nervous systems. To decrease the potential health risks of heavy metals at shooting ranges, more efficient ventilation, optimization of the number of gunshots, and the use of lead-free ammunition should be implemented.