2016
DOI: 10.1002/adma.201603143
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Ultralight Biomass‐Derived Carbonaceous Nanofibrous Aerogels with Superelasticity and High Pressure‐Sensitivity

Abstract: Freeze-casted nanofiber based sponges or aerogels exhibit a hierarchical porous structure. Pore formation is only partially understood. Therefore, we studied the underlying solid templating mechanism. We were able to tailor the secondary pore size between 9.5 and 123 µm while retaining the smaller primary pores known from electrospun nanofiber membranes. To understand the effect of microstructure on the sponges' bulk properties, mass flow through the pores and interaction with the sponges' internal surface wer… Show more

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Cited by 448 publications
(360 citation statements)
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“…Most of the work was nevertheless concentrated on graphene [23] and graphene oxide [24,25], when it was realized that ice-templating could be used to obtain bulk macroporous graphene with dimensions (centimeter) of practical sizes. Aerogels with a density as low as 0.14mg/cm 3 [26] and 0.16 mg/cm 3 [27] have been reported, and there is no reason why we could not obtain even lower densities, starting with even more dilute suspensions. These aerogels have been considered for a variety of applications such as sensors, catalysis, anodes for fuel cells, battery, or super capacitors, adsorption, or even tissue engineering.…”
Section: Ice-templated Aerogelsmentioning
confidence: 99%
“…Most of the work was nevertheless concentrated on graphene [23] and graphene oxide [24,25], when it was realized that ice-templating could be used to obtain bulk macroporous graphene with dimensions (centimeter) of practical sizes. Aerogels with a density as low as 0.14mg/cm 3 [26] and 0.16 mg/cm 3 [27] have been reported, and there is no reason why we could not obtain even lower densities, starting with even more dilute suspensions. These aerogels have been considered for a variety of applications such as sensors, catalysis, anodes for fuel cells, battery, or super capacitors, adsorption, or even tissue engineering.…”
Section: Ice-templated Aerogelsmentioning
confidence: 99%
“…In this approach, some precursors in conjunction with molecular, supramolecular, or colloidal crystal templates are often used as building blocks for nanotectonic assembly. [53] In the template-directed assembly process, some templates are often used, such as cellulose, [54] electrospun SiO 2 nanofibers, [55,56] and tellurium nanowires (TeNWs). [57] The templates of TeNWs are ultrathin with diameters of 7-9 nm and lengths of several micrometers, which can be prepared by our group in a kilogram scale with a one-pot hydrothermal process.…”
Section: Template-directed Assembly Methodsmentioning
confidence: 99%
“…[170] Copyright 2016, Nature Publishing Group. the strain or pressure induced by radial artery waves at the wrist or finger tip, [44,57,59,103,120,123,126,139,203] jugular venous pulses at the neck [57,59,151] or ankle brachial artery pulses near the foot. [21] Monitoring of respiration rate is critical in diagnosis of many disorders or diseases such as sleep disorders, asthma and anemia.…”
Section: Health Monitoringmentioning
confidence: 99%
“…[6,138] Numerous materials and configurations have been reported for resistive pressure sensing. Pressure sensitive pathways can be formed using interlocked structures, [139][140][141][142][143][144] percolative networks of nanomaterials, [57,145,146] microfabricated structures (e.g., micropyramids, micropillars), [147][148][149] porous structures (e.g., sponges, foams, porous rubbers) [26,150,151] and so forth. For example, Figure 5a presents the working principle of a pressure sensor using interlocked microdome array.…”
Section: Wearable Tactile Sensorsmentioning
confidence: 99%