Ultraschnelle Klickkonjugation von makromolekularen Bausteinen bei Raumtemperatur

Inglis, Andrew J.; Sinnwell, Sebastian; Stenzel, Martina H.; Barner‐Kowollik, Christopher

doi:10.1002/ange.200805993

Cited by 103 publications

(148 citation statements)

References 28 publications

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“…iBA [223] St [223,224] 385 [104] 388 [104] 389 [104] (Continued) MAA [225] MAA-b-St [225] S Br Ϫ ϩ S N 64 [226,227] St [226] S S Si(OCH 3 ) 3…”

Section: *mentioning

confidence: 99%

“…266 [209] St [223,224,418] St [419] 267* [34] S S S S S S 268* S S AN [420] AN [420] AN/MA [420] AN/MMA [420] A See footnote A of Table 3. B See footnote B of Table 3.…”

Section: Hnmentioning

confidence: 99%

“…[209,223,224,418,419,484,485] The process has also been developed as a route to block copolymers [223,418] and star polymers. [224,418,484] Other End-Group Modification Processes PNVP chain ends formed with xanthate RAFT agents are susceptible to hydrolysis and can be converted into aldehyde chain ends (Scheme 12).…”

Section: Click Reactionsmentioning

confidence: 99%

“…[502] Star Polymers by 'Grafting-To' Various combinations of RAFT, ATRP, click, ring opening polymerization, and other methods have been used to synthesize star polymers, including mikto-arm stars. [174,223,224,330,418,514] Hetero-Diels-Alder coupling was used to synthesize a 12-armed star as shown in Scheme 26 from a star polymer precursor prepared by ATRP and a PSt macro-RAFT agent. [418] ZЈ S …”

Section: Use Of Multi-raft Agentsmentioning

confidence: 99%

See 3 more Smart Citations

Living Radical Polymerization by the RAFT Process - A Second Update

Moad¹,

Rizzardo²,

Thang³

2009

Aust. J. Chem.

906

720

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This paper provides a second update to the review of reversible deactivation radical polymerization achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of reversible addition-fragmentation chain transfer (RAFT) that was published in June 2005 (Aust. J. Chem. 2005, 58, 379-410). The first update was published in November 2006 (Aust. J. Chem. 2006, 59, 669-692). This review cites over 500 papers that appeared during the period mid-2006 to mid-2009 covering various aspects of RAFT polymerization ranging from reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses and a diverse range of applications. Significant developments have occurred, particularly in the areas of novel RAFT agents, techniques for end-group removal and transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

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“…iBA [223] St [223,224] 385 [104] 388 [104] 389 [104] (Continued) MAA [225] MAA-b-St [225] S Br Ϫ ϩ S N 64 [226,227] St [226] S S Si(OCH 3 ) 3…”

Section: *mentioning

confidence: 99%

“…266 [209] St [223,224,418] St [419] 267* [34] S S S S S S 268* S S AN [420] AN [420] AN/MA [420] AN/MMA [420] A See footnote A of Table 3. B See footnote B of Table 3.…”

Section: Hnmentioning

confidence: 99%

Section: Click Reactionsmentioning

confidence: 99%

Section: Use Of Multi-raft Agentsmentioning

confidence: 99%

See 2 more Smart Citations

Living Radical Polymerization by the RAFT Process - A Second Update

Moad¹,

Rizzardo²,

Thang³

2009

Aust. J. Chem.

906

720

View full text Add to dashboard Cite

show abstract

“…We have recently provided an example of an ultra-fast click reaction, which occurs under ambient conditions without the use of catalysts in a few minutes employing hetero DielsAlder chemistry. [18] The provision of ultra-rapid click chemistries that run to completion within a few minutes at ambient temperature elevates the concept to a level where the modular conjugation of well-defined polymeric building blocks more closely resembles the clicking of lego-blocks.…”

Section: Introductionmentioning

confidence: 99%

Has Click Chemistry Lead to a Paradigm Shift in Polymer Material Design?

Barner‐Kowollik

Inglis

2009

Macro Chemistry & Physics

Self Cite

132

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Has the introduction of the click chemistry concept by Sharpless and colleagues in 2001 lead to a paradigm shift in how we approach the design of macromolecular materials; or is it simply a relatively inconsequential re‐branding exercise of already existing and slightly optimized but well‐tried and tested reactions as some critics would have it? The current Trend Article analyses the situation by examining a series of select macromolecular research fields to shed light on this question, providing an unambiguous answer: The focusing of polymer chemists through the click concept on what constitutes a powerful modular chemical transformation to generate a specific polymeric material is a defining element in contemporary synthetic polymer chemistry, transcending a specific reaction. Without the introduction of the click philosophy several classes of innovative materials and polymer designs would not have been realized.magnified image

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Synthetic and Physicochemical Aspects of Advanced Stimuli‐Responsive Polymers

Kuckling

Urban

2011

Handbook of Stimuli‐Responsive Materials

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Ultraschnelle Klickkonjugation von makromolekularen Bausteinen bei Raumtemperatur

Cited by 103 publications

References 28 publications

Living Radical Polymerization by the RAFT Process - A Second Update

Living Radical Polymerization by the RAFT Process - A Second Update

Has Click Chemistry Lead to a Paradigm Shift in Polymer Material Design?

Synthetic and Physicochemical Aspects of Advanced Stimuli‐Responsive Polymers

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