Ultrasonic study of molecular interaction in Binary liquid mixture at 308 K

Ubagaramary, D.

doi:10.9790/5736-0250119

Cited by 3 publications

(2 citation statements)

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“…Aniline is an organic compound containing a phenyl group attached to an amino group, used extensively in various manufacturing industries. , It is utilized in the preparation of polymers, synthetic dyes, vulcanization of rubber, fungicides, and herbicides . In addition to these, aniline is used to prepare polyurethane which further helps in building thermal foam insulation for refrigerators and buildings. , Some work has already been done on this prototypical aromatic amine (aniline) with different organic components − but still no data is available on thermodynamic studies of aniline with ethylene glycols (EGs).…”

Section: Introductionmentioning

confidence: 99%

Thermodynamic Interactions Study of Some Ethylene Glycols in Aqueous Aniline Solutions at Different Temperatures: An Acoustical and Volumetric Approach

et al. 2018

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With densities and ultrasonic speeds, interactions of aniline with ethylene glycol, diethylene glycol, and triethylene glycol are measured at T = (293.15−308.15) K. From the densities, the (apparent molar and partial molar) volumes, V ϕ and V ϕ 0 are computed. The apparent specific volume υ ϕ and partial specific volume υ ϕ 0 are also evaluated from density data. The (apparent molar and partial molar) isentropic compressions, K ϕ,s and K ϕ,s o have been evaluated from measured ultrasonic speeds. The transfer properties such as partial molar isentropic compression and partial molar volumes of transfer (ΔK ϕ,s o and ΔV ϕ 0 ) are also determined utilizing density and ultrasonic speed data. The pair and the triplet interaction coefficients are computed from partial molar isentropic compression and partial molar volumes of transfer. The partial molar expansibility (∂V ϕ 0 /∂T) p and second order derivative (∂ 2 V ϕ 0 /∂T 2 ) p are also calculated. The parameters hence obtained are conferred in terms of solute−solute or solute−solvent interactions succeeding in the present ternary system.

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Section: Introductionmentioning

confidence: 99%

Thermodynamic Interactions Study of Some Ethylene Glycols in Aqueous Aniline Solutions at Different Temperatures: An Acoustical and Volumetric Approach

et al. 2018

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“…Ubagaramary and Neeraja [7] measured ultrasonic velocity, density and other related parameters and their excess values in the mixtures containing IBMK and aniline & IBMK and ethyl aniline.…”

Section: Introductionmentioning

confidence: 99%