A proposed
BiO(ClBr)(1–x)/2I
x–n
solid solution
containing abundant iodine vacancies has been constructed through
a facile solvothermal treatment strategy. Fascinatingly, the iodine-vacancy
BiO(ClBr)(1–x)/2I
x–n
solid solution exhibits an outstanding
visible-light photocatalytic degradation property for the environmentally
hazardous pollutants of methyl orange, tetracycline, and phenol solutions,
which is credited to the synergistic effect of iodine vacancies and
the solid solution. By manipulating the molar ratios of Cl, Br, and
I, the band structure of the solid solution attained is controlled,
enabling the samples to maximize the harvest of visible light and
to possess strong oxidation features. More importantly, the construction
of iodine vacancies is bound to modulate the local surface atomic
structure and promotes the efficiency of the separation of photogenerated
carriers. Given these, the microstructure and physicochemical and
photoelectrochemical properties of the photocatalysts are fully characterized
in a series. In addition, the iodine-vacancy BiO(ClBr)(1–x)/2I
x–n
solid solution has a stable crystal structure that permits
favorable recyclability even after multiple cycles of degradation.
This study sheds light on the significance of the simultaneous existence
of vacancy and the solid solution for the enhanced performance of
photocatalysts and opens up new insights for sustainable solar–chemical
energy conversion.