Ultraviolet and Visible Absorption Spectra

Bailey, Margaret L.

doi:10.1002/9780470186596.ch11

Chemistry of Heterocyclic Compounds: A Series of Monographs

1973

DOI: 10.1002/9780470186596.ch11

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Ultraviolet and Visible Absorption Spectra

Margaret L. Bailey

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1984

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Linear condensation polymers of aromatic 1,3‐diamines with 3‐pyridinealdehyde

Kharas

Litt

1984

J. Polym. Sci. Polym. Chem. Ed.

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In the presence of one equivalent of acid, m‐phenylenediamine and 2‐methyl m‐phenylenediamine react with pyridine‐3 aldehyde with C alkylation to produce linear polymers, poly(4,6‐R‐methylene m‐phenylenediamine) and poly(4,6‐R‐methylene 2‐methyl m‐phenylenediamine). These were characterized by UV, IR, and NMR spectroscopy. Comparison with model compounds confirmed the above structures. A secondary reaction noted at 25°C and higher for the polymer was the oxidative coupling of two neighboring aromatic diamines to produce substituted 2,7‐diamino acridine groups along the chain.

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Linear condensation polymers of aromatic 1,3‐diamines with 3‐pyridinealdehyde

Kharas

Litt

1984

J. Polym. Sci. Polym. Chem. Ed.

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Ultraviolet and Visible Absorption Spectra

Cited by 1 publication

References 45 publications

Linear condensation polymers of aromatic 1,3‐diamines with 3‐pyridinealdehyde

Linear condensation polymers of aromatic 1,3‐diamines with 3‐pyridinealdehyde

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