Umsetzungen von Metall-und Metalloidverbindungen mit mehrfunktionellen Molekülen, XXXIV Darstellung von Sulfmamidoboranen / Reactions of Metal and Metalloid Compounds with Polyfunctions! Molecules, XXXIV Synthesis of Sulfinamidoboranes

Abstract

<jats:title>Abstract</jats:title><jats:p> Sulfinamidoboranes are prepared by cleavage of the Si-N-bond </jats:p><jats:p>1. of N-methyl-N-trimethylsilyl-methyl-sulfinamide with haloborane derivatives (1-4), and </jats:p><jats:p>2. of N,N-organyl-trimethylsilylaminoboranes with methylsulfinylchloride N-methyl-N-trimethylsilyl-methylsulfinamide (9) is obtained from heptamethyldisilazane with methylsulfinylchloride. The compounds were characterized by analytical and spectrocopic (MS; NMR: <jats:sup>1</jats:sup>H, <jats:sup>11</jats:sup>B) methods.</jats:p>