Un nouveau calorimetre de solution: Le calsol

Thermodynamic properties of illite, smectite and beidellite by calorimetric methods: Enthalpies of formation, heat capacities, entropies and Gibbs free energies of formation

“…The calorimeter was calibrated by dissolving a THAM (2-amino-2-hydroxymethyl-propane-1,3-diol) crystal in a solution of hydrochloric acid (0.12 M), in the same conditions as for the experiments of Ganteaume et al (1991).…”

“…Enthalpies of dissolution at 298.15 K were measured in a hydrofluoric and nitric acid solution with a highly sensitive Tian-Calvet isothermal calorimeter, the Calsol calorimeter (Ganteaume et al, 1991). The calorimetric vessel, made of a HF-resistant epoxy resin, was half filled with the solution and contained a small vessel filled with the sample, which was maintained above the solution.…”

Mixing enthalpies of solid solutions (Cs1−x,Rbx)NO3 at T=(298.15 and 473.15)K

“…We choose pure water as a solvent for measurements of the dissolution enthalpies at T = 298.15 K using two kinds of calorimeters: the Calset (IM2NP, Marseille) and the Isoperibolic (LTA, Tunis) calorimeter, which were described elsewhere in previous works [26,27].…”

Application of Solution Calorimetry to the Prediction of 20.15[(2.038 + x)SiO<sub>2</sub>-(1.457 － x)Na<sub>2</sub>O]-2.6-P<sub>2</sub>O<sub>5</sub>-26.95CaO Glass Bioactivity

“…HF calorimetric experiments were performed with a swinging calorimeter. The calorimeter and standard procedures have been described previously [14,15] and so only a brief description will be given below. Thermopiles consisting of hundreds of chromel-alumel thermocouples were inserted into an aluminum block isotherm.…”

“…The calorimeter was calibrated by using the heat effect of the well-known enthalpy of dissolution of tris-hydroxy-methylaminomethane in hydrochloric solution [15].…”