Surface
plasmon resonance (SPR) is an interfacial phenomenon, and
the plasmonic sensors are based on the optical excitation of the collective
oscillations of free electrons at a metal–dielectric interface.
Here, we present the new development of an incoherent broadband (IBB)-SPR
probe combining the wavelength interrogation technique with polarization-multiplexing
(PM). The performance characteristics of the so-called PMIBB-SPR strategy
was validated for the detection of nonenzymatic aqueous urea samples
as a representative example for plasmonic sensing with an excellent
wavelength and phase sensitivities of 0.1363 nm/mM and 10.34597 mM/deg,
respectively. We further explored the missing link between plasmonic
polariton resonance (PPR) and polarization modulation via the measurements
of the Stokes parameters of the reflected light. This deepens our
understanding of the fundamentals of polarization-multiplexed SPR
phenomenon at the interface. This study thus paves the way to develop
a new-generation analytical technique with the aim of tracking various
real-time chemical and biological molecular interactions occurring
at the interfaces.