This study presents the impact of mineral deposits (SiO2, Al2O3, and CaCO3) on the
corrosion
behavior of X65 pipeline steel in CO2-containing brine
solution with low pH. The study investigates the initiation and propagation
of under deposit corrosion (UDC) using a wire beam electrode (WBE)
partially covered by different mineral deposit layers, in conjunction
with electrochemical measurements and surface characterization. The
results indicate that the corrosion behavior varies, depending on
the characteristics of the deposit. During the test period, the Al2O3-covered steel acted as the main anode with more
negative potential, while the bare steel acted as the cathode. The
SiO2-covered steel acted as the cathode with more positive
potential and a localized FeCO3 layer formed beneath the
silica mineral. The CaCO3-covered steel initially acted
as an anode with a more negative potential but transformed into the
cathode at the end of the test. Additionally, shallow and small pits
were observed beneath the deposits with the depth in the sequence
Al2O3 > SiO2 > CaCO3.