Aerosol jet printing is a noncontact, digital, additive
manufacturing
technique compatible with a wide variety of functional materials.
Although promising, development of new materials and devices using
this technique remains hindered by limited rational ink formulation,
with most recent studies focused on device demonstration rather than
foundational process science. In the present work, a systematic approach
to formulating a polymer-stabilized graphene ink is reported, which
considers the effect of solvent composition on dispersion, rheology,
wetting, drying, and phase separation characteristics that drive process
outcomes. It was found that a four-component solvent mixture composed
of isobutyl acetate, diglyme, dihydrolevoglucosenone, and glycerol
supported efficient ink atomization and controlled in-line drying
to reduce overspray and wetting instabilities while maintaining high
resolution and electrical conductivity, thus overcoming a trade-off
in deposition rate and resolution common to aerosol jet printing.
Biochemical sensors were printed for amperometric detection of the
pesticide parathion, exhibiting a detection limit of 732 nM and a
sensitivity of 34 nA μM–1, demonstrating the
viability of this graphene ink for fabricating functional electronic
devices.