An amine-based surfactant, Duomeen
TTM, was evaluated for foam
flooding in carbonate rock at high temperature (120 °C), high
salinity (22% total dissolved solids), and CO2–oil
miscible conditions. We demonstrate enhanced oil recovery by utilizing
CO2 foam under miscible conditions in the presence of crude
oil. The foam was generated in situ by both co-injection and surfactant
alternating gas injection modes. Foam transport and propagation were
characterized as a function of the foam quality, shear rate, permeability,
surfactant concentration, and method of injection. Finally, we utilize
the experimental results to obtain the parameters for the STARS foam
model by optimizing multiple variables related to the dry out, shear
thinning, and surfactant concentration effects on foam transport.
Enhanced oil recovery utilizing CO2 foam under miscible
conditions in the presence of SMY crude oil was able to decrease oil
saturation to 3.0%. It was also determined that significantly more
injected pore volumes were required for the foam to reach the steady
state in the presence of SMY crude oil. A foam simulation process
in a heterogeneous reservoir is conducted applying the parameters
obtained. The TTM CO2 foam generated significantly reduces
the mobility of CO2 in the high permeability layers, which
results in an improved swept volume in the low permeability zone that
significantly improves oil recovery when epoil = 1 and fmoil = 0.5.
Oil saturation parameters play important roles in the effectiveness
of CO2 foam: large epoil and small fmoil will reduce the
efficiency for TTM CO2 foam.