This paper analyses remotely sensed data over a part of the Psammitic Rocks in Efon-Alaaye and Environs to elucidate its geology and structural framework as well as delineate the potential zones of mineralization. The study area belongs to the Precambrian Basement Complex terrain of Southwestern Nigeria and lies within the eastern unit of the Ilesha schist belt. The lithologic units comprise schistose quartzites, quartz schists, quartz-mica-schists, and granitic gneisses. Landsat 8 satellite imagery and Shuttle Radar Topography Mission imagery (SRTM), both of path 190 and row 055, were used for the purpose of this study. A total of 138 lineaments of total length of 147.948 Km, were automatically extracted from both data. Rose diagram showed that the lineaments are bi-directional, with major lineaments trending NE-SW, E-W and the subsidiary ones in the NW-SE direction. These lineaments are mostly mapped on the schistose quartzites. Also, N-S trending faults were mapped from the Digital Elevation Model map generated from the SRTM data which was confirmed to be reverse fault based on field studies. The mineral alteration map generated revealed signatures of gold, iron oxides and silica minerals, while the mineralization potential map was done with reference to established geological settings of the area in conjunction with the structural elements such as folds, faults, joints and fractures mapped and measured on the field. These structures are typical of gold mineralization and associated metallic minerals in the Ilesha schist belt. This study also confirmed that mineralization in the study area is structurally controlled and type of mineralization is epigenetic in nature as a result of favorable ground preparation.