Nanostructured bainitic steels exhibit an optimum strength/toughness combination as a consequence of their extremely fine structure. They have also demonstrated potential for wear-resistance applications. The aim of this work was to develop bearing steels by the multi-scale control of complex ferritic structures, designed using atomic transformation theory and processed by novel heat treatments. Based on the results, the new ball bearings outperformed conventional grades, approaching more expensive material options. the structure comes from the extremely thin platelets of bainitic ferrite, but also dislocation forests and solution strengthening. It is known from X-ray diffraction (XRD) analyses and confirmed by atom probe tomography (APT) that bainitic ferrite contains much more carbon in solid solution than it is consistent with paraequilibrium thermodynamics conditions [12][13][14][15].The different strength-ductility combinations observed in nanostructured bainite are associated with the stress and strain-induced martensitic transformation of retained austenite during tensile testing [9,11,[16][17][18][19][20]. Additionally, the formation of twins in austenite films has been identified as a strain hardening mechanism contributing to ductility in these structures [20].Complex properties, such as wear resistance and fatigue endurance, must be also assessed before the commercialization of novel bainitic steels. Earlier work [4,5] showed that the wear resistance of carbide-free bainitic steels was comparable to that of the best pearlitic grades. In the context of rail applications, Chang [6] investigated the rolling/sliding wear performance of several high silicon bainitic steels, along with detailed microstructural characterization. Results showed lower wear rates in carbide-free bainitic steels and a beneficial effect of the austenite embedded in the sub-micron ferritic structure. In fact, Zhang et al. [21] found that high silicon bainitic steels show better wear resistance than much harder martensite. Likewise, Yang et al. [22] observed that material performance improved when the transformation temperature decreased and a nano-scale bainitic structure was formed.These studies hint at the considerable benefits of nanostructured bainite against several wear and surface damage mechanisms [7,23,24]. Retained austenite is considered to be critical for improving wear resistance in these structures, since this phase provides hardening by transformation into martensite [23,25]. It is well-known that hardness affects the stress needed to deform the material in the rolling/sliding contact, and it is an important factor in decreasing material loss. Wang et al. [26] found that the austenite in the vicinity of a sliding surface decomposes under the influence of high shear strains, resulting in the formation of an extremely fine structure with grains of ferrite only about 3 nm in size.Rolling contact fatigue (RCF) has also been determined to be a key mechanism of material removal in the wear performance of nanostructured bai...