2022
DOI: 10.1016/j.jcis.2022.07.086
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Understanding nonlinear composition dependency of enantioselectivity in chiral separation using mixed micelle

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Cited by 5 publications
(7 citation statements)
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“…In this work, new equations based on the regular solution theory were derived. The equation could express the nonlinear enantioselectivity of the mixed micelle system with a less elaborated technique than in the previous report [35]. The positive nonlinearity was attributed to the difference in interaction parameter (DB AB ) between two enantiomers A and B. Nonlinear composition dependency of the enantioselectivity has been reported earlier by the other researcher but elucidating the mechanism behind it was hampered by the absence of the theory that can express the phenomenon in the equation [31].…”
Section: Discussionmentioning
confidence: 86%
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“…In this work, new equations based on the regular solution theory were derived. The equation could express the nonlinear enantioselectivity of the mixed micelle system with a less elaborated technique than in the previous report [35]. The positive nonlinearity was attributed to the difference in interaction parameter (DB AB ) between two enantiomers A and B. Nonlinear composition dependency of the enantioselectivity has been reported earlier by the other researcher but elucidating the mechanism behind it was hampered by the absence of the theory that can express the phenomenon in the equation [31].…”
Section: Discussionmentioning
confidence: 86%
“…The method was applied to the previously reported system (Table 1) [35]. Figure 3 describes the result of applying regular solution theory for the enantioseparation of racemic solutes (Figure 3a) by the MEKC method using achiral/chiral mixed micelle as the pseudostationary phase.…”
Section: Application Of the Theories To The Experimental Systemmentioning
confidence: 99%
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