Micropatterning
is considered a promising strategy for improving
the performance of electrochemical devices. However, micropatterning
on ceramic is limited by its mechanically fragile properties. This
paper reports a novel imprinting-assisted transfer technique to fabricate
an interlayer structure in a protonic ceramic electrochemical cell
with a micropatterned electrolyte. A dense proton-conducting electrolyte,
BaCe0.7Zr0.1Y0.1Yb0.1O3−δ, is micropatterned in a chevron shape with
the highest aspect ratio of patterns in electrode-supported cells
to the best of our knowledge, increasing surface areas of both electrode
sides more than 40%. The distribution of relaxation time analysis
reveals that the chevron-patterned electrolyte layer significantly
increases the electrode contact areas and active electrochemical reaction
sites at the vicinity of the interfaces, contributing to enhanced
performances of both the fuel cell and electrolysis operations. The
patterned cell demonstrates improved fuel cell performance (>45%)
and enhances electrolysis cell performance (30%) at 500 °C. This
novel micropatterning technique is promising for the facile production
of layered electrochemical cells, further opening a new route for
the performance enhancement of ceramic-based electrochemical cells.