Understanding the role of structural distortions on the transport properties of Ar ion irradiated SrTiO3 thin films: X-ray absorption investigation

Abstract

We report the evolution of structural distortions on the pulsed laser deposited SrTiO3 (STO) thin films irradiated by 1 MeV Ar ion beam and their response in the electrical and thermoelectric properties correlated with their electronic structures. The structural studies reveal a modification in the crystalline nature resulting in the synergistic enhancement of resistivity and the Seebeck coefficient due to ion irradiation-induced oxygen vacancies and augment the power factor to ∼17 μW m−1K−2, which is 2.5 times higher than the pristine STO. An in-depth analysis of the conduction mechanism using various theoretical models implies the role of band conduction and Mott-variable range hopping. Further, the changes in the local electronic structures are reflected in the variation in the Ti–O bond length and the density of unoccupied states that alter the spectral intensities and chemical shifts and are responsible for the observed enhancement in the thermoelectric properties. The above results indicate the significance of the ion beams to tune the electrical and thermoelectric properties.

Recent Progress in the Application of Ion Beam Technology in the Modification and Fabrication of Nanostructured Energy Materials

“…The PF and zT of the proton irradiated Bi 2 Te 3 samples were as high as 432 μW m –1 K –2 and 0.18 ± 0.03, respectively. Asokan et al reported the evolution of structural distortions in the pulsed laser deposited SrTiO 3 (STO) thin films irradiated by 1 MeV Ar ion beam, where their response in the electrical and thermoelectric properties correlated with their electronic structures. The structural studies reveal a modification in the crystalline nature resulting in the synergistic enhancement of resistivity and the Seebeck coefficient due to ion irradiation-induced oxygen vacancies and augmentation of the power factor to 17 μW m –1 K –2 , which is 2.5 times higher than the pristine STO.…”

“…Ji et al successfully used 12 MeV proton irradiation to create defects in Bi 2 Te 3 , leading to the enhancement of thermoelectric properties (Figure 14a). 93 The decoupling of interdependent thermoelectric parameters (high electrical conductivity, high Seebeck coefficient, and low MeV Ar ion beam, 94 where their response in the electrical and thermoelectric properties correlated with their electronic structures. The structural studies reveal a modification in the crystalline nature resulting in the synergistic enhancement of resistivity and the Seebeck coefficient due to ion irradiationinduced oxygen vacancies and augmentation of the power factor to 17 μW m −1 K −2 , which is 2.5 times higher than the pristine STO.…”

A comprehensive review of oxygen vacancy modified photocatalysts: synthesis, characterization, and applications

“…7a). Bhogra et al 99 utilized Ar + ion beam irradiation to induce oxygen vacancies in SrTiO 3 films. Zhang et al 100 generated oxygen vacancies in WO 3 through H + beam bombardment (Fig.…”