Understanding the Solid‐Electrolyte‐Interface (SEI) Formation in Glyme Electrolyte Using Time‐Of‐Flight Secondary Ion Mass Spectrometry (ToF‐SIMS)

Abstract

Lithium‐ion batteries are commonly used for energy storage due to their long lifespan and high energy density, but the use of unsafe electrolytes poses significant health and safety concerns. An alternative source is necessary to maintain electrochemical efficacy. This research demonstrates new safe glyme‐based electrolytes for silica/carbon (SiOx/C) nanocomposite derived from Australian rice husk (RH). The quality of SiOx/C was preserved by using deep eutectic solvent‐based pre‐treatment and single‐step carbonization, which was confirmed through the X‐ray analysis of the crystalline phase of silica. The electrochemical assessment of SiOx/C anode using various glyme‐based electrolytes for LIBs was carried out. Among them, the resultant half cells based on diglyme electrolyte is superior to others with the first discharge capacity at 1274 mAh/g and a reversible discharge capacity of 759.7 mAh/g. Ex‐situ SEM and Time‐of‐Flight Secondary Ion Mass Spectrometry (ToF‐ SIMS) analysis of the electrode indicated that diglyme not only improves the capacity but also sustains the electrode architecture for longer cycle life with more LiF‐based components and also showed the absence of HF components. Importantly, the addition of fluoroethylene carbonate (FEC) additive enhanced the cycling stability. These results provide a new perspective on developing advanced SiOx/C anode using glyme electrolytes for LIBs.