High-dimensional discrete chaotic systems have a wide range of engineering applications, while the chaotic synchronization method is the key to confidential communication applications. Based on the proposed discriminant theorem for high-order polynomial chaotic mapping, in this paper, a hybrid inverse generalization and inverse projection synchronization method for high-dimensional discrete chaotic systems is constructed. The method increases the flexibility of synchronization control by designing to enable the coexistence of inverse projection synchronization and inverse generalized synchronization in chaotic systems, by specifically using an invertible and adjustable constant diagonal matrix to extend the control capability of the error system. Meanwhile, this paper proposed the validity of this hybrid synchronization scheme based on the multi-stationary chaotic system for the first time, through comparison, it is certified that the multi-stationary discrete chaotic synchronization system introduced in this paper not only has complex dynamics behavior but also has a faster synchronization speed. Meanwhile, this paper proposed the validity of this hybrid synchronization scheme based on the multi-stationary chaotic system for the first time, through comparison, it is certified that the multi-stationary discrete chaotic synchronization system introduced in this paper not only has complex dynamics behavior but also has a faster synchronization speed. Finally, a transmission system based on hybrid synchronization is also designed in this paper, where experiments and analyses of cryptographic transmission of pictures are carried out, and the results of the analyses show that the system has higher security and a larger key space.