2022
DOI: 10.3390/cryst12081122
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Unexpected Formation of a Silicon-Centered Spirocyclic Oligosiloxane Bearing Eight Pendant Ferrocene Units

Abstract: An intriguing but rare silicon-centered spirocyclic compound, spiro[5.5]octaferrocenylpentasiloxane (4) featuring silicon fused six-membered ferrocenyl-functionalized siloxane rings, has been obtained during the thermally induced transformation of triferrocenylsilane Fc3Si–H (1) into triferrocenylsilanol Fc3Si–OH (2), when N,N-dimethylformamide (DMF) was used as a solvent in the presence of the metal carbonyl Mo(CO)6. The unexpected formation of the maximally ferrocenyl substituted silicon centered spirocyclic… Show more

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