A systematic study has been carried out on the growth of pure and doped tetrafluoro phthalate crystals. The lattice parameters find through powder X-ray diffraction analysis for the grown pure and doped crystals. The functional groups, stretching are found through FT-IR and FT-Raman spectroscopical analysis, optical, absorption studies through UV-Vis analysis, thermal studies under TG/DTA analysis, through Vickers test and LCR metre the microhardness and dielectric studies were also carried out for the grown pure and dyes doped crystals. The SHG efficiency of the pure and dyes doped TFP crystals were also studied using Nd:YAG Q-switched laser. The results of these investigations are discussed in this paper.