In this article, the ray tracing method is studied beyond the classical
geometrical theory. The trajectories are here regarded as geodesics in a
Riemannian manifold, whose metric and topological properties are those induced
by the refractive index (or, equivalently, by the potential). First, we derive
the geometrical quantization rule, which is relevant to describe the orbiting
bound-states observed in molecular physics. Next, we derive properties of the
diffracted rays, regarded here as geodesics in a Riemannian manifold with
boundary. A particular attention is devoted to the following problems: (i)
modification of the classical stationary phase method suited to a neighborhood
of a caustic; (ii) derivation of the connection formulae which enable one to
obtain the uniformization of the classical eikonal approximation by patching up
geodesic segments crossing the axial caustic; (iii) extension of the eikonal
equation to mixed hyperbolic-elliptic systems, and generation of complex-valued
rays in the shadow of the caustic. By these methods, we can study the creeping
waves in diffractive scattering, describe the orbiting resonances present in
molecular scattering beside the orbiting bound-states, and, finally, describe
the generation of the evanescent waves, which are relevant in the nuclear
rainbow.Comment: 30 pages, 2 figure