2013
DOI: 10.1016/j.apsusc.2013.02.021
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Uniform β-Co(OH)2 disc-like nanostructures prepared by low-temperature electrochemical rout as an electrode material for supercapacitors

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Cited by 68 publications
(20 citation statements)
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“…As the active material loading increased from 2.6 to 9.3 mg cm À2 , only a slight decrease was observed at low or high current densities. To further evaluate the electrochemical performances of the Co 1.5 Ni 1.5 S 4 electrodes with different loadings, the Coulombic efficiencies (CE) of the Co 1.5 Ni 1.5 S 4 electrodes at various loadings were calculated using Equation S(4) [31] and are provided in Fig. 4c.…”
Section: Resultsmentioning
confidence: 99%
“…As the active material loading increased from 2.6 to 9.3 mg cm À2 , only a slight decrease was observed at low or high current densities. To further evaluate the electrochemical performances of the Co 1.5 Ni 1.5 S 4 electrodes with different loadings, the Coulombic efficiencies (CE) of the Co 1.5 Ni 1.5 S 4 electrodes at various loadings were calculated using Equation S(4) [31] and are provided in Fig. 4c.…”
Section: Resultsmentioning
confidence: 99%
“…4 presents some very broad vibration bands, particularly the not well-dened OH stretching band at about 3573 cm À1 , the weak bending mode of the interlayer water molecule at 1640 cm À1 , the bands at 1351 cm À1 and 1490 cm À1 due to the C]O vibration of absorbed CO 2 and the carbonate ions from the dissolution of CO 2 in water 38,39 and the band at 594 cm À1 arising from the metal-oxygen stretching or metal-hydroxyl bending vibration modes in hydroxides 26,27 (Table 1). 4 presents some very broad vibration bands, particularly the not well-dened OH stretching band at about 3573 cm À1 , the weak bending mode of the interlayer water molecule at 1640 cm À1 , the bands at 1351 cm À1 and 1490 cm À1 due to the C]O vibration of absorbed CO 2 and the carbonate ions from the dissolution of CO 2 in water 38,39 and the band at 594 cm À1 arising from the metal-oxygen stretching or metal-hydroxyl bending vibration modes in hydroxides 26,27 (Table 1).…”
Section: Resultsmentioning
confidence: 99%
“…1(A) and (b)), which is in good agreement with the standard spectrum of b-Co(OH) 2 (JCPDS No. 30-0443) [11,12]. No peaks of any other phases or impurities are detected, demonstrating high purity of the asprepared b-Co(OH) 2 sample.…”
Section: Methodsmentioning
confidence: 76%
“…3(c) shows the CV of the prepared b-Co(OH) 2 /NF electrode in 2 M KOH at the scan rate of 10 mV/s. The curve owns two pairs of redox peaks p1 versus p2 and p3 versus p4 [5,11,13], indicating that the capacitance characteristics are governed by faradaic reactions, distinct from that of the electric double-layer capacitance, which will produce a CV curve close to an ideal rectangular shape. Peak p1 is due to the oxidation of Co(OH) 2 to CoOOH and peak p2 is for the reverse process; peak p3 is attributed to oxidation of CoOOH to CoO 2 , p4 is therefore ascribed to the reduction of CoO 2 to CoOOH.…”
Section: Resultsmentioning
confidence: 96%