“…4 presents some very broad vibration bands, particularly the not well-dened OH stretching band at about 3573 cm À1 , the weak bending mode of the interlayer water molecule at 1640 cm À1 , the bands at 1351 cm À1 and 1490 cm À1 due to the C]O vibration of absorbed CO 2 and the carbonate ions from the dissolution of CO 2 in water 38,39 and the band at 594 cm À1 arising from the metal-oxygen stretching or metal-hydroxyl bending vibration modes in hydroxides 26,27 (Table 1). 4 presents some very broad vibration bands, particularly the not well-dened OH stretching band at about 3573 cm À1 , the weak bending mode of the interlayer water molecule at 1640 cm À1 , the bands at 1351 cm À1 and 1490 cm À1 due to the C]O vibration of absorbed CO 2 and the carbonate ions from the dissolution of CO 2 in water 38,39 and the band at 594 cm À1 arising from the metal-oxygen stretching or metal-hydroxyl bending vibration modes in hydroxides 26,27 (Table 1).…”