2015
DOI: 10.1002/kin.20915
|View full text |Cite
|
Sign up to set email alerts
|

Unimolecular Rate Constants for the HF and HCl Elimination Reactions from Chemically Activated CF2ClSH

Abstract: Chemically activated CF 3 SH, CFCl 2 SH, and CF 2 ClSH were formed through combination of SH and CF 3 , CFCl 2 , and CF 2 Cl radicals, respectively. The SH radical was prepared by abstraction of an H-atom from H 2 S by the halocarbon radical produced during photolysis of (CF 3 ) 2 C=O, (CFCl 2 ) 2 C=O, or (CF 2 Cl) 2 C=O. 1,2-HX (X = F, Cl) elimination reactions were observed from CF 3 SH, CFCl 2 SH, and CF 2 ClSH with products detected by GC-MS. The combination reaction of CF 2 Cl radicals with SH radicals pr… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 43 publications
(61 reference statements)
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?