“…This observation provides a motivation for the introduction of PC into the deposition process because it can significantly affect the kinetic processes on the electrode and thereby affect nanostructure formation. For example, in other alloy systems (generally using aqueous baths), waveforms with "off-time" have been found to affect aspects of the deposits such as chemical composition 32,[49][50][51] and homogeneity, 49 surface roughness, 49,52,53 grain size distribution, 47,51,52,54,55 and texture. 50 Reverse pulse waveforms have also been found to significantly affect such coating attributes.…”