By generalizing Ledrappier's criterion [Mesures d'èquilibre d'entropie complètement positive, in Systèmes dynamiques II-Varsovie, number 50 in Astérisque, Société mathématique de France, 1977, pp. 251-272] for the K-property of equilibrium states, we extend the criterion to subadditive potentials. In particular, supposing that the unique equilibrium state for a subadditive potential with quasimultiplicativity and bounded distortion is totally ergodic, we show that it has the K-property. We apply this result to subadditive potentials arising from certain classes of matrix cocycles; for the norm potentials of irreducible locally constant cocycles and the singular value potentials of typical cocycles, we show that their unique equilibrium states have the K-property. This partly generalizes the work of Morris [Ergodic properties of matrix equilibrium states, Ergodic Theory Dyn. Syst. 38(6), 2018, pp. 2295-2320] on irreducible locally constant cocycles and their subadditive equilibrium states.