New J. Chem.
 2021
DOI: 10.1039/d0nj05498d
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Unique reactivity of an α-ketiminopyridine ligand with metal–alkyls: Synthesis and ROP of ε-caprolactone

Miroslav Novák
1
,
Roman Jambor
2
,
Zdeňka Růžičková
3
et al.

Abstract: The α-ketimininopyridine ligand 2-((Me)C=N(C6H3-2,6-iPr2))-6-(OMe)C5H3N (L1) was studied in reactions with metal-alkyls such as MeLi, Et2Zn, Me3Al and Me2AlCl. The reaction of L1 with MeLi led exclusively to the formation of...

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