The transition helicity amplitudes from the proton ground state to the N (1440)1/2 + , N (1520)3/2 − , and ∆(1620)1/2 − resonances (γvpN * electrocouplings) were determined from the analysis of nine independent one-fold differential π + π − p electroproduction cross sections off a proton target, taken with CLAS at photon virtualities 0.5 GeV 2 < Q 2 < 1.5 GeV 2 . The phenomenological reaction model employed for separation of the resonant and non-resonant contributions to this exclusive channel was further developed. The N (1440)1/2 + , N (1520)3/2 − , and ∆(1620)1/2 − electrocouplings were obtained from the resonant amplitudes of charged double-pion electroproduction off the proton in the aforementioned area of photon virtualities for the first time. Consistent results on γvpN * electrocouplings available from independent analyses of several W -intervals with different non-resonant contributions offer clear evidence for the reliable extraction of these fundamental quantities. These studies also improved the knowledge on hadronic branching ratios for the N (1440)1/2 + , N (1520)3/2 − , and ∆(1620)1/2 − decays to the π∆ and ρN final states. These new results provide a substantial impact on the QCD-based approaches that describe the N * structure and demonstrate the capability to explore fundamental ingredients of the non-perturbative strong interaction that are behind the excited nucleon state formation.