We propose a new array configuration composed of multi-scale scalar arrays and a single triangular spatially spread electromagnetic-vector-sensor (SS-EMVS) for high-accuracy two-dimensional (2D) direction-of-arrival (DOA) estimation. Two scalar arrays are placed along x-axis and y-axis, respectively, each array consists of two uniform linear arrays (ULAs), and these two ULAs have different inter-element spacings. In this manner, these two scalar arrays form a multi-scale L-shaped array. The two arms of this L-shaped scalar array are connected by a six-component SS-EMVS, which is composed of a spatially spread dipole-triad plus a spatially spread loop-triad. All the inter-element spacings in our proposed array can be larger than a half-wavelength of the incident source, thus to form a sparse array to mitigate the mutual coupling across antennas. In the proposed DOA estimation algorithm, we perform the vector-cross-product algorithm to the SS-EMVS to obtain a set of low-accuracy but unambiguous direction cosine estimation as a reference; we then impose estimation of signal parameters via rotation invariant technique (ESPRIT) algorithm to the two scalar arrays to get two sets of high-accuracy but cyclically ambiguous direction cosine estimations. Finally, the coarse estimation is used to disambiguate the fine but ambiguous estimations progressively and therefore a multiple-order disambiguation algorithm is developed. The proposed array enjoys the superiority of low redundancy and low mutual coupling. Moreover, the thresholds of the inter-sensor spacings utilized in the proposed array are also analyzed. Simulation results validate the performance of the proposed array geometry.