“…The catalytic hydrogenation of organic functionalities using FLPs has been reported for alkynes, [10] alkenes, [11] ketones, [12] silyl enol ethers, [13] anilines, [14] imines, [15] enamines, [16] amides, [17] aza‐Morita–Baylis–Hillman adducts, [18] esters, [19] and recently for the hydrodehalogenation of benzylhalides [20] . In the case of silyl halides and pseudohalides, the presence of a stoichiometric quantity of a nitrogen base is necessary since the reaction is otherwise endergonic [7c–e] . Interestingly, the group of Rieger reported the cleavage of H 2 with B/N Frustrated Lewis Pairs (amines and perfluorinated triarylboranes) [21] .…”