2017
DOI: 10.1002/zaac.201700208
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Unprecedented Connection Mode of [V16Sb4O42(H2O)]8– Cluster Anions by Mn2+ Centered Complexes: Solvothermal Synthesis and Properties of {[Mn(teta)]4V16Sb4O42(H2O}n·[(H2O)12]n

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Cited by 3 publications
(3 citation statements)
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References 40 publications
(146 reference statements)
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“…A similar network topology was observed in the compound {[Mn(teta)] 4 V 16 Sb 4 O 42 } n [(H 2 O) 12 ] n [54] but also remarkable differences should be mentioned. In the structure of the Sb‐POV compound two unique layers are present and adjacent cluster anions are joined by neighbouring cis‐trans complexes, whereas in the structure of the title compound the clusters are connected by cis ‐ cis or trans ‐ trans complexes.…”
Section: Resultssupporting
confidence: 70%
“…A similar network topology was observed in the compound {[Mn(teta)] 4 V 16 Sb 4 O 42 } n [(H 2 O) 12 ] n [54] but also remarkable differences should be mentioned. In the structure of the Sb‐POV compound two unique layers are present and adjacent cluster anions are joined by neighbouring cis‐trans complexes, whereas in the structure of the title compound the clusters are connected by cis ‐ cis or trans ‐ trans complexes.…”
Section: Resultssupporting
confidence: 70%
“…The Mn−O bond lengths to μ 3 −O 2− bridging centers are in tendency significantly shorter (2.162(4)–2.189(4) Å) than those to μ 2 −O 2− centers (2.217(4)–2.291(4) Å) except for the Mn4 atom surrounded by five N atoms (Mn−μ 2 −O: 2.513 Å). The Mn−N bonds vary from 2.244 to 2.311 Å (Table S2), and are in the range reported for [Mn(dien) 2 ] 2+ containing compounds [22,30–39] . The N−Mn−N, N−Mn−O and O−Mn−O angles (Table S2) indicate significant distortions compared to regular polyhedra with coordination number six.…”
Section: Resultsmentioning
confidence: 66%
“…[29] Two of the four unique Mn S2), and are in the range reported for [Mn(dien) 2 ] 2 + containing compounds. [22,[30][31][32][33][34][35][36][37][38][39] The NÀ MnÀ N, NÀ MnÀ O and OÀ MnÀ O angles (Table S2) indicate significant distortions compared to regular polyhedra with coordination number six. Forced by the integration of Mn1 and Mn2 into the structure of the As-POV cluster shell, the polyhedra around both cations contain four O atoms forming a distorted rectangular plane, and one N and one O atom located above the plane leads to formation of an oblique triangular prism with one triangle comprising three O 2À ligands and the other consisting of two O and one N atom.…”
Section: Introductionmentioning
confidence: 99%