Unravel crystallization kinetics of V(V) electrolytes for all-vanadium redox flow battery by in situ Raman spectroscopy

Wan, Zaoyan; Li, Site; Chen, Ping; Yeung, Frank; Nie, Zimin; Liang, Yangang; Wang, Yilin; Feng, Ruozhu; Wang, Zheming; Zhang, Xin; Wang, Wei

doi:10.1007/s42114-023-00635-2

Adv Compos Hybrid Mater

2023

DOI: 10.1007/s42114-023-00635-2

|View full text |Cite

Unravel crystallization kinetics of V(V) electrolytes for all-vanadium redox flow battery by in situ Raman spectroscopy

Zaoyan Wan,

Site Li,

Ping Chen

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 6 publications

References 47 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH₄⁺

Zhu,

2024

Small

View full text Add to dashboard Cite

A new methodological design is proposed for carbon dots (CDs)‐based crystallization‐induced phosphorescence (CIP) materials via one‐step self‐assembled packaging controlled by NH4+. O‐phenylenediamine (o‐PD) as a nitrogen/carbon source and the ammonium salts as oxidants are used to obtain CDs supramolecular crystals with a well‐defined staircase‐like morphology, pink fluorescence and ultralong green room‐temperature phosphorescence (RTP) (733.56 ms) that is the first highest value for CDs‐based CIP materials using pure nitrogen/carbon source by one‐step packaging. Wherein, NH4+ and o‐PD‐derived oxidative polymers are prerequisites for self‐assembled crystallization so as to receive the ultralong RTP. Density functional theory calculation indicates that NH4+ tends to anchor to the dimer on the surface state of CDs and guides CDs to cross‐arrange in an X‐type stacking mode, leading to the spatially separated frontier orbitals and the through‐space charge transfer (TSCT) excited state in turn. Such a self‐assembled mode contributes to both the small singlet–triplet energy gap (ΔEST) and the fast inter‐system crossing (ISC) process that is directly related to ultralong RTP. This work not only proposes a new strategy to prepare CDs‐based CIP materials in one step but also reveals the potential for the self‐assembled behavior controlled by NH4+.

show abstract

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH₄⁺

Zhu,

2024

Small

View full text Add to dashboard Cite

show abstract

A novel vanadium-copper rechargeable battery for solar energy conversion and storage

Lin,

Wang,

Zhang

et al. 2024

Chemical Engineering Journal

View full text Add to dashboard Cite

Emerging polyoxometalate clusters-based redox flow batteries: Performance metrics, application prospects, and development strategies

Han,

Sun,

et al. 2024

Energy Storage Materials

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Unravel crystallization kinetics of V(V) electrolytes for all-vanadium redox flow battery by in situ Raman spectroscopy

Cited by 6 publications

References 47 publications

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH₄⁺

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH₄⁺

A novel vanadium-copper rechargeable battery for solar energy conversion and storage

Emerging polyoxometalate clusters-based redox flow batteries: Performance metrics, application prospects, and development strategies

Contact Info

Product

Resources

About

Unravel crystallization kinetics of V(V) electrolytes for all-vanadium redox flow battery by in situ Raman spectroscopy

Cited by 6 publications

References 47 publications

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH4+

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH4+

A novel vanadium-copper rechargeable battery for solar energy conversion and storage

Emerging polyoxometalate clusters-based redox flow batteries: Performance metrics, application prospects, and development strategies

Contact Info

Product

Resources

About

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH₄⁺

A Facile One‐Step Self‐Assembly Strategy for Novel Carbon Dots Supramolecular Crystals with Ultralong Phosphorescence Controlled by NH₄⁺