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Carbides, especially transition metal carbides (TMCs) and non‐metallic silicon carbides (SiCs), have registered wide applications in catalysis, superconductivity, semiconductor, and the like. Systematic studies have demonstrated the essential role of carbon in finetuning the atomic structures and electronic properties of carbides to improve their catalytic performance, superconducting transition temperature, and semiconductor bandgap. These advancements have positioned carbides as efficient substitutes for noble metals and crucial components in technological innovations. Scanning tunneling microscopy (STM) has emerged as a powerful technique in these studies, providing high‐resolution visualization and mapping of the surface geometric and electronic structures of these functionalized carbides. This review mainly focuses on the key aspects like the structures and properties of the aforementioned TMC and SiC surfaces unraveled by STM, aiming at understanding the fundamentals behind the state‐of‐the‐art technologies and advanced applications of the carbide‐involved functional systems. A very brief perspective on this topic is also provided at the end.
Carbides, especially transition metal carbides (TMCs) and non‐metallic silicon carbides (SiCs), have registered wide applications in catalysis, superconductivity, semiconductor, and the like. Systematic studies have demonstrated the essential role of carbon in finetuning the atomic structures and electronic properties of carbides to improve their catalytic performance, superconducting transition temperature, and semiconductor bandgap. These advancements have positioned carbides as efficient substitutes for noble metals and crucial components in technological innovations. Scanning tunneling microscopy (STM) has emerged as a powerful technique in these studies, providing high‐resolution visualization and mapping of the surface geometric and electronic structures of these functionalized carbides. This review mainly focuses on the key aspects like the structures and properties of the aforementioned TMC and SiC surfaces unraveled by STM, aiming at understanding the fundamentals behind the state‐of‐the‐art technologies and advanced applications of the carbide‐involved functional systems. A very brief perspective on this topic is also provided at the end.
From 1990 to 2024, this study presents a groundbreaking bibliometric and sentiment analysis of nanocomposite literature, distinguishing itself from existing reviews through its unique computational methodology. Developed by our research group, this novel approach systematically investigates the evolution of nanocomposites, focusing on microstructural characterization, electrical properties, and mechanical behaviors. By deploying advanced Boolean search strategies within the Scopus database, we achieve a meticulous extraction and in-depth exploration of thematic content, a methodological advancement in the field. Our analysis uniquely identifies critical trends and insights concerning nanocomposite microstructure, electrical attributes, and mechanical performance. The paper goes beyond traditional textual analytics and bibliometric evaluation, offering new interpretations of data and highlighting significant collaborative efforts and influential studies within the nanocomposite domain. Our findings uncover the evolution of research language, thematic shifts, and global contributions, providing a distinct and comprehensive view of the dynamic evolution of nanocomposite research. A critical component of this study is the “State-of-the-Art and Gaps Extracted from Results and Discussions” section, which delves into the latest advancements in nanocomposite research. This section details various nanocomposite types and their properties and introduces novel interpretations of their applications, especially in nanocomposite films. By tracing historical progress and identifying emerging trends, this analysis emphasizes the significance of collaboration and influential studies in molding the field. Moreover, the “Literature Review Guided by Artificial Intelligence” section showcases an innovative AI-guided approach to nanocomposite research, a first in this domain. Focusing on articles from 2023, selected based on citation frequency, this method offers a new perspective on the interplay between nanocomposites and their electrical properties. It highlights the composition, structure, and functionality of various systems, integrating recent findings for a comprehensive overview of current knowledge. The sentiment analysis, with an average score of 0.638771, reflects a positive trend in academic discourse and an increasing recognition of the potential of nanocomposites. Our bibliometric analysis, another methodological novelty, maps the intellectual domain, emphasizing pivotal research themes and the influence of crosslinking time on nanocomposite attributes. While acknowledging its limitations, this study exemplifies the indispensable role of our innovative computational tools in synthesizing and understanding the extensive body of nanocomposite literature. This work not only elucidates prevailing trends but also contributes a unique perspective and novel insights, enhancing our understanding of the nanocomposite research field.
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