Unravelling the benefits of transition-metal-co-doping in lanthanide upconversion nanoparticles

Mohanty, Sonali; Kaczmarek, Anna

doi:10.1039/d2cs00495j

Cited by 36 publications

(22 citation statements)

References 118 publications

(179 reference statements)

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“…iv) Doping effect Heteroatoms doping is a common method to change the chemical properties and intrinsic structure of MoS 2 cathode to enhance its electrochemical performances, which is an advisable modification strategy according to previous reports. [82][83][84][85][86][87][88] Heteroatoms doping have been widely employed in energy storage, and it can effectively improve the electronic conductivity, enlarge the interlayer spacing, and enhance the hydrophilicity of the active material. [89] Particularly, nitrogendoped is normally used to boost electron transport, shorten ion insertion/extraction pathways, and decrease ion diffusion energy barrier, [90] and it has been studied to improve the electrochemical properties of MoS 2 cathode in aqueous ZIBs.…”

Section: Wwwadvancedsciencenewscommentioning

confidence: 99%

Recent Advances of Transition Metal Sulfides/Selenides Cathodes for Aqueous Zinc‐Ion Batteries

Shuai

Liu

et al. 2022

Advanced Energy Materials

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Rechargeable aqueous zinc‐ion batteries (ZIBs) have aroused tremendous attention in energy storage system due to their high safety, eco‐friendliness, low cost, and for their good compatibility. Transition metal sulfides and selenides are considered to be promising cathodes for aqueous ZIBs owing to their unique layered structure and tunable interlayer spacing for the accelerating diffusion and reversible intercalation of hydrated Zn2+. However, their practical applications are severely impeded by some defects, such as the inferior electronic conductivity, large ion diffusion energy barrier, and bad cyclic stability. In this review, the various modification strategies including phase engineering, defect engineering, interlayer intercalation, in situ electrochemical oxidation, hybridization, doping effects, and surface modification are categorized and highlighted to improve the electrochemical properties of transition metal sulfides and selenides cathode materials, which are discussed and summarized corresponding to particular modification strategies. Finally, several key breakthrough directions such as mechanism exploration technology, electrolyte strategies, synergistic engineering, high‐capacity conversion‐type, high‐voltage cathode materials, and rocking‐chair type batteries are proposed to further push forward the development of aqueous ZIBs, to guide the design of advanced‐properties cathode materials for aqueous ZIBs.

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Section: Wwwadvancedsciencenewscommentioning

confidence: 99%

Recent Advances of Transition Metal Sulfides/Selenides Cathodes for Aqueous Zinc‐Ion Batteries

Shuai

Liu

et al. 2022

Advanced Energy Materials

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“…Lanthanide‐doped is a classic strategy for constructing upconversion materials. [ 83 ] Yan and co‐workers synthesized ytterbium(III)‐ and erbium(III)‐doped porphyrinic MOF ( MOF 3 , Figure 5c) as an upconversion PS. [ 84 ] The energy was transferred from the upconversion nanocore to the MOF shell at NIR irradiation, producing a significant amount of ROS, accompanied by the release of hypoxia‐responding chemotherapy prodrug tirapazamine.…”

Section: Metal‐based Photosensitizers Trigger Icdmentioning

confidence: 99%

Recent Progress in Photodynamic Immunotherapy with Metal‐Based Photosensitizers

et al. 2022

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Cancer ranks as a leading cause of death. There is an urgent need to develop minimally invasive methods to eradicate tumors and prevent their recurrence. As a light‐driven modality, photodynamic therapy takes advantage of high tumor selectivity and low normal tissue damage. However, it shows poor potential for preventing tumor recurrence. Immunotherapy is currently being used as an alternative treatment for the control of malignant diseases. Although immunotherapy can establish long‐time immune memory and efficiently protects treated patients from cancer relapse, its clinical efficacy is limited by the minority of patients’ responding rate. Recently, photodynamic immunotherapy, which utilizes photosensitizers as an immunotherapy trigger to exert synergistic effects of photodynamic therapy and tumor immunotherapy, has attracted considerable interest. Like all the newly proposed treatments, there is still room for improvement. In this mini review, the progress in photodynamic immunotherapy with metal‐based photosensitizers is summarized. It is hoped that this review can give a broad update on photodynamic immunotherapy and inspire readers.

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“…9,10 It has been proposed that the codoping of transition metals successfully improves the up-conversion performance. 11,12 Thus, the transition metal molybdate may play a vital role to enhance the emission arising from rare earth ions. The substitution of tungstate with molybdate can be a good choice since they have an equivalent ionic charge and comparable ionic radius.…”

Section: Introductionmentioning

confidence: 99%

Upconverting temperature sensors with high activation energy and low pump threshold

Prasad

Kumar

2023

New J. Chem.

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Unravelling the benefits of transition-metal-co-doping in lanthanide upconversion nanoparticles

Abstract: In this review we provide an overview of the current knowledge on lanthanide upconversion materials co-doped with transition metals. We focus on how the co-dopants affect the host lattice and the energy transfer processes.

Cited by 36 publications

References 118 publications

Recent Advances of Transition Metal Sulfides/Selenides Cathodes for Aqueous Zinc‐Ion Batteries

Recent Advances of Transition Metal Sulfides/Selenides Cathodes for Aqueous Zinc‐Ion Batteries

Recent Progress in Photodynamic Immunotherapy with Metal‐Based Photosensitizers

Upconverting temperature sensors with high activation energy and low pump threshold

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