Chongwe River Catchment, a sub-catchment of the Zambezi River Basin, has been experiencing changes in land use/land cover (LULC) and in its hydrology. This study aims to assess the impact of LULC changes on the catchment's hydrological components such as streamflow, evapotranspiration and water abstractions. LULC change data, detected from the 1984, 1994, 2014 and 2017 USGS Landsat imagery using a maximum likelihood supervised classifier, were integrated into the WEAP Model along with soil, slope and hydro-climate data. The results showed that between 1984 and 2017 built-up area increased by 382.77% at 6.97 km 2 /year, irrigated agriculture increased by 745.62% at 1.70 km 2 /year, rainfed farms/ranch/grassland increased by 14.67% at 14.53 km 2 /year, forest land decreased by 41.11% at 22.33 km 2 /year and waterbodies decreased by 73.95% at 0.87 km 2 /year. Streamflow increased at a rate of 0.13 Mm 3 per annum in the wet seasons and showed a high variation with flow volume of 79.68 Mm 3 in February and 1.01 Mm 3 in September. Annual actual evapotranspiration decreased from 840.6 mm to 796.3 mm while annual water abstraction increased from 8.94 mm to 23.2 mm from the year 1984 to 2017. The pattern of LULC change between 1984 and 2017 has negatively impacted the hydrology of the Chongwe River Catchment. From these findings, an integrated catchment management and protection approach is proposed to mitigate the negative impacts of LULC dynamics on hydrological components in the Chongwe River Catchment.Sustainability 2019, 11, 6415 2 of 13 rainfall to water yield through altering an ecosystem's hydrological characteristics such as infiltration, evapotranspiration, and groundwater recharge capacity [7]. Understanding the impact of LULC change on watershed hydrology at catchment level could help to (i) identify and alleviate the occurrence of critical shifts in hydrologic processes, (ii) assess the water resources availability and their sustainable utilization under increasing population, agricultural expansion, and industrialization, and (iii) formulate appropriate policies to improve land use planning and spatial developments [8][9][10]. In this regard, direct field observations and spatial-temporal analysis of LULC change from remote sensing data play a crucial role in providing historical and current information to understand the effects on river ecosystem, guide urban densification and limit unsustainable urban expansion at catchment level [11][12][13].The Chongwe River Catchment, with a population of over 834,359 people, is a sub-catchment of the Zambezi River Basin [14,15], and has been experiencing changes in LULC influenced by the fast-growing population, infrastructure and social-economic developments particularly in Lusaka City [15][16][17]. About 45% of Lusaka City falls within the Chongwe River Catchment [16]. The majority of the people in the catchment depend on the Chongwe River and its main tributaries for their domestic, agriculture, industrial and socio-economic water needs. The demand for water has dra...