2024
DOI: 10.1021/acs.inorgchem.4c03241
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Unsymmetric Ir2 and RhIr Dinuclear Complexes Supported by a Linear Tetraphosphine meso-dpmppp, Showing High Reactivity for O2, H2, and HCl

Takayuki Nakajima,
Momoko Kotani,
Yuki Maeda
et al.

Abstract: Unsymmetric dinuclear Ir(I) complexes, [Ir 2 Cl 2 (L)(mesodpmppp)] (L = XylNC (1aIr 2 ), t BuNC (1bIr 2 ), CO (1cIr 2 )), were synthesized using meso-Ph 2 PCH 2 P(Ph)(CH 2 ) 3 P(Ph)CH 2 PPh 2 (meso-dpmppp), which supports cis-P,P (M 1 ) and trans-P,P (M 2 ) metal sites, and exhibited high reactivity for O 2 , H 2 , and HCl. The IrRh heterodinuclear complexes, [M 1 M 2 Cl 2 (L)(mesodpmppp)] (1xM 1 M 2 ) (M 1 M 2 = IrRh, RhIr; L = XylNC, CO (x = a, c)), were also synthesized and used together with the Rh 2 compl… Show more

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