Untersuchungen �ber das morpholin-N-dithiocarbonsaure Morpholinium (MDCM) als Reagens in der quantitativen Analytik. X

Likussar, W.

doi:10.1007/bf01198047

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2007

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“…38 Potentiometric titrations for determination of gallium and indium ions using dialkyldithiocarbamates have also been carried out. [42][43][44][45][46] 2 Ga(S 2 PPh 2 )], a dimeric structure has been suggested, although the complex has not been isolated. 24 Unlike organometallic derivatives, the chloro complexes, [MCl 3-n {S 2 P(OR)} n ] (n = 1 or 2), display molecular ion peaks in their mass spectra.…”

Section: Synthesesmentioning

confidence: 99%

Gallium(III) and indium(III) dithiolate complexes: Versatile precursors for metal sulfides

Ghoshal

Jain

2007

J Chem Sci

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The chemistry of classical and organometallic complexes of gallium and indium with dithiolate ligands, i.e., dithiocarboxylates, xanthates, dithiocarbamates, dithiophosphates, dithiophophinates and dithioarsenates, has been reviewed. Synthesis, spectroscopic and structural aspects of these complexes are described. Their emerging role as single source molecular precursors for the preparation of metal sulfide thin films and nano-particles has been discussed.

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