Unusual 1,1–2,2-isomers of Mo2Cl4(PR3)2R′CN)2. Compounds with RCH2CH2CNa and R′CH3, CH3CH2 and CH(CH3)2

Cotton, F. Albert; Daniels, Lee M.; Haefner, Steven C.; Walke, Erik N.

doi:10.1016/0020-1693(95)04950-9

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Cited by 10 publications

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Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl₄(PH₂R)] (R=2,4,6‐Prⁱ₃C₆H₂, Cyclohexyl, Cp′=C₅H₄Me)

et al. 1997

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Various substituted cyclopentadienyl molybdenum(V) tetrachlorides are reduced on reaction with PH-functionallzed lithium phosphanides to give the corresponding cyclopentadienyl molybdenum(II1) dichloro which can then react with further lithium reagent, yielding terminal phosphanido. diphosphanyl, and diphosphene complexes [5]. We attempted to prevent the reduction of Mo(V) by employing a primary phosphane instead of the highly reducing lithium reagents for the introduction of a P-functionalized ligand.Here we report on the preparation, spectroscopic properties and molecular structures of the first organometallic molybdenum(V) complexes with primary phosphane ligands, [Cp'MoCI4(PH2R)] [Cp' = C5H4Me, R = 2,4,6-Pr!3C6H2 (l), Cy (211.

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Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl₄(PH₂R)] (R=2,4,6‐Prⁱ₃C₆H₂, Cyclohexyl, Cp′=C₅H₄Me)

et al. 1997

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Organometallic Molybdenum(V) Complexes with Primary Phosphine Ligands. Syntheses, Spectroscopic Properties and Molecular Structures of [Cp°MoCl₄(PH₂R)] (R = Bu^t, 1‐Ad, Cy, Ph, 2, 4, 6‐Me₃C₆H₂, 2, 4, 6‐Prⁱ₃C₆H₂, Cp° = C₅EtMe₄)

Felsberg

Blaurock

Junk

et al. 2004

Zeitschrift anorg allge chemie

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Molybdenum Compounds

Cotton

Multiple Bonds Between Metal Atoms

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Unusual 1,1–2,2-isomers of Mo2Cl4(PR3)2R′CN)2. Compounds with RCH2CH2CNa and R′CH3, CH3CH2 and CH(CH3)2

Cited by 10 publications

References 22 publications

Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl₄(PH₂R)] (R=2,4,6‐Prⁱ₃C₆H₂, Cyclohexyl, Cp′=C₅H₄Me)

Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl₄(PH₂R)] (R=2,4,6‐Prⁱ₃C₆H₂, Cyclohexyl, Cp′=C₅H₄Me)

Organometallic Molybdenum(V) Complexes with Primary Phosphine Ligands. Syntheses, Spectroscopic Properties and Molecular Structures of [Cp°MoCl₄(PH₂R)] (R = Bu^t, 1‐Ad, Cy, Ph, 2, 4, 6‐Me₃C₆H₂, 2, 4, 6‐Prⁱ₃C₆H₂, Cp° = C₅EtMe₄)

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Unusual 1,1–2,2-isomers of Mo2Cl4(PR3)2R′CN)2. Compounds with RCH2CH2CNa and R′CH3, CH3CH2 and CH(CH3)2

Cited by 10 publications

References 22 publications

Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R=2,4,6‐Pri3C6H2, Cyclohexyl, Cp′=C5H4Me)

Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R=2,4,6‐Pri3C6H2, Cyclohexyl, Cp′=C5H4Me)

Organometallic Molybdenum(V) Complexes with Primary Phosphine Ligands. Syntheses, Spectroscopic Properties and Molecular Structures of [Cp°MoCl4(PH2R)] (R = But, 1‐Ad, Cy, Ph, 2, 4, 6‐Me3C6H2, 2, 4, 6‐Pri3C6H2, Cp° = C5EtMe4)

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Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl₄(PH₂R)] (R=2,4,6‐Prⁱ₃C₆H₂, Cyclohexyl, Cp′=C₅H₄Me)

Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands — Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl₄(PH₂R)] (R=2,4,6‐Prⁱ₃C₆H₂, Cyclohexyl, Cp′=C₅H₄Me)

Organometallic Molybdenum(V) Complexes with Primary Phosphine Ligands. Syntheses, Spectroscopic Properties and Molecular Structures of [Cp°MoCl₄(PH₂R)] (R = Bu^t, 1‐Ad, Cy, Ph, 2, 4, 6‐Me₃C₆H₂, 2, 4, 6‐Prⁱ₃C₆H₂, Cp° = C₅EtMe₄)