2009
DOI: 10.1016/j.molstruc.2009.09.044
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Unusual 2:3:2 complex of DABCO mono-betaine with HCl and H2O studied by X-ray diffraction, DFT calculations and spectroscopic methods

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Cited by 17 publications
(3 citation statements)
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“…An analogous propeller conformation was observed in 1,4-diazobicyclo [2.2.2] octane derivatives [28,56].…”
Section: Crystal Structuresupporting
confidence: 64%
See 1 more Smart Citation
“…An analogous propeller conformation was observed in 1,4-diazobicyclo [2.2.2] octane derivatives [28,56].…”
Section: Crystal Structuresupporting
confidence: 64%
“…The center of gravity of this absorption, m H , calculated for the 1500-400 cm À1 region, from the ratio of P Am/ P m, is around 900 cm À1 . A similar broad absorption is present in the IR spectra of 2:1 complexes of other betaines with acids [13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30] and of type A acid salts of carboxylic acid [3,57]. Notable is the absence of any distinct absorption in the region above 1800 cm À1 , except for the stretching CH 3 , CH 2 and C-H vibrations, which are also observed in the spectrum of QNBuÁH 2 OÁHBr [39].…”
Section: Vibrational Spectramentioning
confidence: 80%
“…DABCO mono-betaine trihydrochloride dihydrate was prepared according to the literature method of Barczyń ski et al (2009). The title compound was synthesized by adding a solution of cadmium chloride (1.141 g, 5 mmol) to a solution of DABCO mono-betaine trihydrochloride dihydrate (2.429 g, 5 mmol) in water (50 ml).…”
Section: Synthesis and Crystallizationmentioning
confidence: 99%