Unusual Metalloporphyrin Complexes of Rhenium and Technetium

Tsutsui, M.; Hrung, C. P.; Ostfeld, D.; Srivastava, Tanuja; Cullen, D. L.

doi:10.21236/ada012430

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Carbonyls1

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1983

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“…In the centrosymmetric complex both Tc-atoms are bonded to the porphyrin, one above and one below the plane of the macrocycle [204], The monotechnetium porphyrin [monohydrogen mesoporphyrinlXdimethylesterato] tricarbonyltechnetium(I) [205,206] and the heterodinuclear porphyrin [tricarbonyl technetium(I)]^-[mesoporphyrinlXdimethyl esterato]-[tricarbonylrhenium(I)] could also be prepared [207],…”

Section: Carbonylsmentioning

confidence: 99%

The Present Status of Technetium Chemistry

Schwochau

1983

Radiochimica Acta

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Technetium is the lightest artificial radioelement. Traces of "Tc occur in the earth's crust, weighable amounts are formed in high yield by the fission of 2 3 5 U. The laboratory handling of "Tc needs no special radiation protection. The chemical behaviour and the complex chemistry of the transition element resemble closely those of the homologous element rhenium. Some uses of technetium are demonstrated.

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Section: Carbonylsmentioning

confidence: 99%

The Present Status of Technetium Chemistry

Schwochau

1983

Radiochimica Acta

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Unusual Metalloporphyrin Complexes of Rhenium and Technetium

Cited by 1 publication

References 13 publications

The Present Status of Technetium Chemistry

The Present Status of Technetium Chemistry

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