Unveiling favorable synergy of tubules-like NiMoSe2 with defect-rich borocarbonitride over graphene or MXene for efficient hydrogen evolution reaction electrocatalysis

Beere, Hemanth Kumar; Shantharaja,; Yatish, K.V.; Aravind, K.; Ghosh, Debasis; Balakrishna, R. Geetha; Pramoda, K.

doi:10.1016/j.ijhydene.2023.12.122

International Journal of Hydrogen Energy

2024

DOI: 10.1016/j.ijhydene.2023.12.122

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Unveiling favorable synergy of tubules-like NiMoSe2 with defect-rich borocarbonitride over graphene or MXene for efficient hydrogen evolution reaction electrocatalysis

Hemanth Kumar Beere,

Shantharaja,

K.V. Yatish

et al.

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2024

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Cited by 4 publications

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Nickel Molybdenum Selenide (NiMoSe₂) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives

Verma,

Raju,

Verma

et al. 2024

ChemistrySelect

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Binary transition metal dichalcogenides (BTMDs) have attracted a lot of researchers to exploit their unique properties for different applications in various fields, mainly in energy and environment. Surprisingly, there are no attempts of utilizing BTMDs materials particularly nickel molybdenum selenide (NiMoSe2) as a catalyst support for organic transformations. Reusable catalysts are better alternatives to the transition metal‐free protocols for the synthesis of heterocyclic compounds. Herein, we report a NiMoSe2 BTMD catalyst with Lewis acidic (transition metal) and strongly basic (selenide) sites for the regioselective synthesis of 2,3,5‐tri(het)aryl‐pyrroles from β‐thioxoketone precursors. The present method is capable of giving the expected products in good to excellent yields (up to 80%). Different substituents like ester, cyano, alkyl, trifluoromethyl, methoxy, and halogens have shown tolerance under optimized reaction conditions. The recyclability and reusability of the catalyst was checked for five catalytic cycles without notable loss in reactivity.

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Nickel Molybdenum Selenide (NiMoSe₂) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives

Verma,

Raju,

Verma

et al. 2024

ChemistrySelect

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Rapid and eco-friendly ultrasonic exfoliation of transition metal dichalcogenides supported on sonogel-nanocarbon black: A non-precious electrocatalyst for hydrogen evolution reaction

Berni,

García-Guzmán,

Alcántara

et al. 2024

International Journal of Hydrogen Energy

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Rhombohedrally stacked layered transition metal dichalcogenides and their electrocatalytic applications

Pramoda,

Chithaiah,

Rao

2024

Nanoscale

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Unveiling favorable synergy of tubules-like NiMoSe2 with defect-rich borocarbonitride over graphene or MXene for efficient hydrogen evolution reaction electrocatalysis

Cited by 4 publications

References 108 publications

Nickel Molybdenum Selenide (NiMoSe₂) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives

Nickel Molybdenum Selenide (NiMoSe₂) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives

Rapid and eco-friendly ultrasonic exfoliation of transition metal dichalcogenides supported on sonogel-nanocarbon black: A non-precious electrocatalyst for hydrogen evolution reaction

Rhombohedrally stacked layered transition metal dichalcogenides and their electrocatalytic applications

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Unveiling favorable synergy of tubules-like NiMoSe2 with defect-rich borocarbonitride over graphene or MXene for efficient hydrogen evolution reaction electrocatalysis

Cited by 4 publications

References 108 publications

Nickel Molybdenum Selenide (NiMoSe2) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives

Nickel Molybdenum Selenide (NiMoSe2) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives

Rapid and eco-friendly ultrasonic exfoliation of transition metal dichalcogenides supported on sonogel-nanocarbon black: A non-precious electrocatalyst for hydrogen evolution reaction

Rhombohedrally stacked layered transition metal dichalcogenides and their electrocatalytic applications

Contact Info

Product

Resources

About

Nickel Molybdenum Selenide (NiMoSe₂) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives

Nickel Molybdenum Selenide (NiMoSe₂) Nanostructures: A Binary Transition Metal Dichalcogenide for Regioselective Synthesis of 2,3,5‐Tri Substituted Pyrrole Derivatives