Conventional treatment of a mixed-metal wastewater consists ofhydroxide precipitation of the metals at an alkaline pH, followed by removal of the resulting solids by simple sedimentation and sometimes filtration. Hexavalent chromium removal is preceded by reduction to the less soluble trivalent chromium. Sulfur compounds (sodium sulfite, etc.) are commonly used reducing agents with the reaction carried out at pH 2 to 3. Treatment complexity results from the need to maintain separate acidic and alkaline cesses. Efficient alkaline reduction of hexavalent c romium would consolidate these two processes, simplify the treatment of mixed-metals wastewater, and reduce acid and base usage.
Bennet [I] and Watson [Z] stated that an acidic pH (lessof Technology in 1963. He also received B.S. and M.S. degrees in Chemical Engineering from I.I.T. in 1957 and 1959. His major areas of interest include process instrumentation and control with an emphasis on digital computer applications. Environmental M r w r (Vol. 3, No. 1)