Upgrading Biomass Wastes to Graphene Quantum Dots with White-Light-Emitting Features in the Solid State

Abstract

The emergence of bio-based carbonaceous materials for various applications has attracted significant attention during the last few years. Here, we report a rapid, efficient, and reproducible microwave-assisted synthesis of graphene quantum dots (GQDs) with identical features irrespective of the nature of biomass waste investigated. The synthesized GQDs were fully characterized by X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, transmission electron microscopy, and dynamic light scattering. The nanoparticles displayed narrow sizes of 1–2 nm and high solubility in polar solvents such as water and ethanol. The protocol described herein is advantageous in comparison to dealing with the synthesis of GQDs from biomass waste previously reported since our protocol is faster owing to the use of microwave heating and the avoidance of dialysis for the purification step. Furthermore, in solution, the water-soluble particles showed excitation-dependent photoluminescence ranging from blue to orange emission wavelengths. Interestingly, thin films displayed white-light emission under 325 nm UV-light excitation, while aggregation-induced quenching was usually observed, opening the way for their potential use as a phosphor in white-light-emitting diodes.