Upgrading of the biomass-derived platform compound 5-hydroxymethylfurfural to high-value chemicals: an environment-friendly corrosion inhibitor

Ai, Wenying; Liu, Kexin; Cao, Zhenfeng; Zou, Jiawei; Li, Ping; Cui, Siwen; Yang, Haiyan; Yang, Yu; Cao, Jian; Jiao, Mingli

doi:10.1039/d3gc04254e

Green Chem.

2024

DOI: 10.1039/d3gc04254e

|View full text |Cite

Upgrading of the biomass-derived platform compound 5-hydroxymethylfurfural to high-value chemicals: an environment-friendly corrosion inhibitor

Wenying Ai,

Kexin Liu,

Zhenfeng Cao

et al.

Abstract: Herein, an environment-friendly corrosion inhibitor was synthesised from the bio-based platform compound 5-hydroxymethylfurfural. Weight loss and electrochemical experiments demonstrated that this inhibitor is an efficient mixed-type corrosion inhibitor in HCl...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 60 publications

(76 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Experimental and Quantum Chemical Studies of a Green Corrosion Inhibitor for Mild Steel in Acidic Chloride Solution

Zou,

Ai,

Zhao

et al. 2024

ChemistrySelect

View full text Add to dashboard Cite

A green corrosion inhibitor was prepared from the bio‐based platform compound 5‐hydroxymethylfurfural through a green synthetic route, which avoid the use of toxic reagent. The inhibition performance and mechanism of this compound for the corrosion of mild steel in 0.1 M HCl was investigated by using the weight loss experiments, polarization measurements, EIS measurements and quantum chemical calculations. The corrosion inhibition efficiency by weight loss measurement (ηWLM%) of this inhibitor can reach up to 90.3 % at 303 K with 1.2 mM concentration. Moreover, the electrochemical experiments revealed that this corrosion inhibitor acts as a mixed‐type inhibitor. Thermodynamic studies gave the values of the standard Gibbs free energy , fall within the range of −20 kJ/mol to −40 kJ/mol, suggested the adsorption of this compound is a spontaneous process involving both physisorption and chemisorption. In addition, quantum chemical calculations were conducted to further validate the formation of an effective absorption layer by this inhibitor on metal surfaces, which showed that the electron density iso‐surfaces of HOMO was mainly distributed on chloride ions, while LUMO tended to be distributed on furan rings and aldehyde groups. Besides, the other quantum chemical parameters of this inhibitor were also calculated to explore the molecular activity, such as, the molecular volume (ν, 333.105 Å), global hardness (η, 4.706 eV), global softness (σ, 0.2125 eV), electronegativity (χ, 4.93 eV), dipolemoment (μ, 13.1429 D) and vertical ionization energy (VIE, 7.2646 eV).

show abstract

Experimental and Quantum Chemical Studies of a Green Corrosion Inhibitor for Mild Steel in Acidic Chloride Solution

Zou,

Ai,

Zhao

et al. 2024

ChemistrySelect

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Upgrading of the biomass-derived platform compound 5-hydroxymethylfurfural to high-value chemicals: an environment-friendly corrosion inhibitor

Abstract: Herein, an environment-friendly corrosion inhibitor was synthesised from the bio-based platform compound 5-hydroxymethylfurfural. Weight loss and electrochemical experiments demonstrated that this inhibitor is an efficient mixed-type corrosion inhibitor in HCl...

Cited by 1 publication

References 60 publications

Experimental and Quantum Chemical Studies of a Green Corrosion Inhibitor for Mild Steel in Acidic Chloride Solution

Experimental and Quantum Chemical Studies of a Green Corrosion Inhibitor for Mild Steel in Acidic Chloride Solution

Contact Info

Product

Resources

About