Uraninite, Coffinite and Ningyoite from Vein-Type Uranium Deposits of the Bohemian Massif (Central European Variscan Belt)

Self Cite

The Bohemian magmatic complex belongs to granitoid plutons of the Central European Variscides. Hydrothermal uranium mineralization evolved in the small uranium deposits Nahošín and Mečichov is associated with N–S shear zones occurring on the SW margin of the Central Bohemian plutonic complex formed by amphibole-bearing biotite granodiorites of the Blatná suite. The purpose of presented study is description of uranium mineralization bounded on brittle shear zones, which is coupled with intense low-temperature hydrothermal alteration of granitic rocks. Uranium mineralization, formed predominantly of coffinite, rare uraninite, and thorite, is accompanied by intense hematitization, albitization, chloritization, and carbonatization of original granitic rocks that could be described as aceites. These alterations are accompanied by the enrichment in U, Ti, Mg, Ca, Na, K, Y, and Zr and depletion in Si, Ba, and Sr. The analyzed coffinite is enriched in Y (up to 3.1 wt % Y2O3). Uraninite is enriched in Th (up to 9.8 wt % ThO2) and thorite is enriched in Zr (up to 5.7 wt % ZrO2). The REE-elements are concentrated in the REE-fluorcarbonate synchysite-(Ce).

Section: Occurrence Of Th-rich Uraninite and Thoritementioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Alteration of Granitoids and Uranium Mineralization in the Blatná Suite of the Central Bohemian Plutonic Complex, Czech Republic

René

2020

Self Cite

“…Uranium is a typical redox sensitive element. It is 'fluid-mobile' when present as oxidized state (U 6+ ) but largely immobile when present as reduced species (U 4+ ) [88][89][90][91][92][93]. Sandstone-hosted U deposits are epigenetic deposits in which U minerals are present as disseminations and mineral replacements primarily in fluvial, lacustrine, and deltaic sandstones [94].…”

Section: Constraints On U Mineralizationmentioning

confidence: 99%

Petrogenetic Constraints of Early Cenozoic Mafic Rocks in the Southwest Songliao Basin, NE China: Implications for the Genesis of Sandstone-Hosted Qianjiadian Uranium Deposits

Yang

Fengjun

et al. 2020

The tectonic inversion of the Songliao Basin during the Cenozoic may have played an important role in controlling the development of sandstone-type uranium deposits. The widely distributed mafic intrusions in the host sandstones of the Qianjiadian U ore deposits provided new insights to constrain the regional tectonic evolution and the genesis of the U mineralization. In this study, zircon U-Pb dating, whole-rock geochemistry, Sr-Nd-Pb isotope analysis, and mineral chemical compositions were presented for the mafic rocks from the Qianjiadian area. The mafic rocks display low SiO2 (44.91–52.05 wt.%), high TFe2O3 contents (9.97–16.46 wt.%), variable MgO (4.59–15.87 wt.%), and moderate K2O + Na2O (3.19–6.52 wt.%), and can be subdivided into AB group (including basanites and alkali olivine basaltic rocks) and TB group (mainly tholeiitic basaltic rocks). They are characterized by homogenous isotopic compositions (εNd (t) = 3.47–5.89 and 87Sr/86Sr = 0.7032–0.7042) and relatively high radiogenic 206Pb/204Pb (18.13–18.34) and Nb/U ratios (23.0–45.6), similar to the nearby Shuangliao basalts, suggesting a common asthenospheric origin enriched with slab-derived components prior to melting. Zircon U-Pb and previous Ar-Ar dating show that the AB group formed earlier (51–47 Ma) than the TB group (42–40 Ma). Compared to the TB group, the AB group has higher TiO2, Na2O, K2O, P2O5, Ce, and HREE contents and Ta/Yb and Sr/Yb ratios, which may have resulted from variable depth of partial melting in association with lithospheric thinning. Combined with previous research, the Songliao Basin experienced: (1) Eocene (~50–40 Ma) lithospheric thinning and crustal extension during which mafic rocks intruded into the host sandstones of the Qianjiadian deposit, (2) a tectonic inversion from extension to tectonic uplift attributed to the subduction of the Pacific Plate occurring at ~40 Ma, and (3) Oligo–Miocene (~40–10 Ma) tectonic uplift, which is temporally associated with U mineralization. Finally, the close spatial relation between mafic intrusions and the U mineralization, dike-related secondary reduction, and secondary oxidation of the mafic rocks in the Qianjiadian area suggest that Eocene mafic rocks and their alteration halo in the Songliao Basin may have played a role as a reducing barrier for the U mineralization.

“…It may have been continuous diffusional Pb loss, episodic recrystallization, or by the formation of secondary uraninite [52,56]. Due to the Pb loss of uraninite, a "chemical age" of uraninite calculated from the EPMA analyses were highly questionable [57][58][59]. Therefore, uraninite in situ Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) U-Pb geochronological research should be carried out, in order to obtain a precise mineralization age for the MHK (No.…”

Section: Pb Loss and Reliability Of The Uraninite U-th-pb Chemical Agesmentioning

confidence: 99%

Geochemistry and Acid Hydrometallurgy Accessibility of Uraninite from Mianhuakeng Granite-Hosted Uranium Deposit, South China

Wang

Sun

et al. 2020

Systematic study of the surface chemical properties of uranium minerals is necessary to improve the uranium ore extracting process. The presented work aims to argue geochemistry and acid hydrometallurgy accessibility of uraninite from the Mianhuakeng (MHK) granite-hosted uranium deposit, South China, which provides insight on this ore extracting domain. Mineralogy, geochemical composition, U–Th–Pb chemical age, and uranium deportment of the uraninite were systematically analyzed by using scanning electron microscope with energy dispersion spectrum (SEM-EDS), an electron probe microanalyzer (EPMA), and x-ray photoelectron spectroscopy (XPS). The results showed that uraninite was intergrowth with coffinite, probably due to uraninite being partly metasomatized into coffinite along the fissures. The major element content of uraninite such as for UO2, SiO2, and CaO were 79.46 ± 2.03 wt%, 6.19 ± 1.36 wt%, and 5.09 ± 0.80 wt%, respectively. Single-point U–Th–Pb chemical ages for uraninite grains were calculated with the EPMA data, and the results showed ages ranging from a few million to dozens of million years, indicating Pb loss after uraninite formed. Uranium deportment in uraninite generally existed in the forms of UO2, U3O8, and UO3, and mostly showed high valence states suggested by XPS. Uranium on the surface of the uraninite grain was partially oxidized by sulfuric acid leaching, which led to tetravalent uranium converting to hexavalent uranium, suggesting uraninite in the MHK uranium deposit is accessible to be leached by sulfuric acid.