2003
DOI: 10.1002/mame.200300012
|View full text |Cite
|
Sign up to set email alerts
|

Use of Acrylic Functionalized (Meth)acrylic Cross‐Linked Polymer Microparticles in Photopolymerized Acrylic Films

Abstract: The effect of reactive (meth)acrylic cross‐linked polymer microparticles (reactive CPM, also called reactive microgels) used as cross‐linking agents has been studied on the thermo‐mechanical properties of different photopolymerized thin films. The matrix was based on the copolymerization of isobornyl acrylate and ethoxy ethoxy ethyl acrylate or butyl acrylate. Various concentrations of CPM were initially blended with the monomers. These solutions were photopolymerized under UV radiation to obtain hard and tran… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1

Citation Types

1
10
0
1

Year Published

2007
2007
2012
2012

Publication Types

Select...
7

Relationship

1
6

Authors

Journals

citations
Cited by 16 publications
(12 citation statements)
references
References 43 publications
1
10
0
1
Order By: Relevance
“…9). Rapid polymerization would lead to low mechanical strength, similar to the literature described 8. The number of grafting chains with short‐chain length or free polymer chains (not grafting any HRM microsphere) increased under fast polymerization rate, and so the short‐terminated chains cannot entangle two vicinal HRM nanoparticles.…”
Section: Resultssupporting
confidence: 64%
See 1 more Smart Citation
“…9). Rapid polymerization would lead to low mechanical strength, similar to the literature described 8. The number of grafting chains with short‐chain length or free polymer chains (not grafting any HRM microsphere) increased under fast polymerization rate, and so the short‐terminated chains cannot entangle two vicinal HRM nanoparticles.…”
Section: Resultssupporting
confidence: 64%
“…It is of interest to gain the possibility for a mild chemical modification of the nanoparticles to design their structure and properties. The nanoparticles with double bonds can be useful as toughening agents for photopolymerized thin films or thermosets 8, 9. The hyaluronic acid (HA)‐based hydrogel materials with HA hydrogel particles embedded in and covalently crosslinked to a secondary network exhibit unique structural and mechanical characteristics 10.…”
Section: Introductionmentioning
confidence: 99%
“…Epoxy/carboxylic acid functional microgels have been used in epoxy matrices to improve their toughness 9. (Meth)acrylate‐functional microgels have been used as crosslinking agents, and their use has improved the mechanical properties of UV curing matrices 10. Water‐based baking paints made from a reactive microgel and melamine–formaldehyde resin showed better coating properties and a better dispersability of aluminum powder compared to conventional paints 11.…”
Section: Introductionmentioning
confidence: 99%
“…Also commonly known as microgels (or sometimes nanogels) for many years, they can be viewed as a new, fourth class of polymers (besides linear, branched macromolecules and macroscopic polymer networks), on the border between molecules and particles [1][2][3]. Due to their nanoscopic size and compact structure, CPMs now find applications in numerous practical and/or industrial fields, for instance as components for binders in organic coatings, nanometric carriers for numerous dyes, pharmaceutical or biochemical compounds used in immuno assays and controlled drug delivery systems [4], or high performance fillers in plastics, thermosetting polymers or coatings [5,6].…”
Section: Introductionmentioning
confidence: 99%